Acylated 2-Iminothiazolines

Kaye, Irving Allan; Parris, Chester L.

doi:10.1021/jo01139a011

Cited by 8 publications

(1 citation statement)

References 3 publications

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“…(72%) (491) Kaye and Parris (489) found that when 2-acetamidothiazoIe (I) was treated with benzyl chloride, the expected compound (III) was not obtained. Instead, I reacted in its tautomeric form (II) to give 2-acetylimino-3-benzylthiazoline (IV) in 39 per cent yield.…”

Section: Cooc2hsmentioning

confidence: 99%

The Chemistry of the Alkali Amides.

Levine¹,

Fernelius²

1954

Chem. Rev.

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This review of the chemistry of the alkali amides is a continuation of two earlier reviews (17) which have appeared on this subject. In the present review the authors have summarized the work on the inorganic and organic chemistry of the alkali amides which has appeared in the literature from 1937 through 1952. In addition, a considerable amount of previously unpublished material is discussed. Whenever possible, the authors have tried to interpret and evaluate critically the material presented and to call attention to those areas of research which have not been investigated or which should be studied further. Although it has not been convenient to discuss all of the present material under the same headings as were used previously, the changes have not been so extensive as to make cross references difficult.

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Section: Cooc2hsmentioning

confidence: 99%

The Chemistry of the Alkali Amides.

Levine¹,

Fernelius²

1954

Chem. Rev.

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Aminothiazoles and Their Derivatives

Barone¹,

Chanon

Gallo³

1979

Chemistry of Heterocyclic Compounds: A Series of Monographs

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Zur Kenntnis des Imidazothiazol‐Ringsystems

Kickhöfen

Kröhnke

1955

Chem. Ber.

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Eine neue Synthese von Imidazothiazol-Derivaten bestiitigt, daB sich Imidazopfidin und -thiazol in ihrer Rildungsart sehr nahe stehen. Auch ihre quartilren Sake zeigen in jeder Hinsicht groBe Analogie. Dagegen unterscheiden Rioh die Vorprodukta der Synthese, nanllich a-Amino-pyridin und -thiazol und z.Tl. nooh mehr deren Acyl-Derivate usw. adfallend voneinander. Die Griinde dafiir werden crortert.Das Ringsystem des Imidazo -(2.1b )t hiazols (I) 2, wurde synthetisiert, als es, im nahen Zusammenhang mit der-Konstitutionsaufkllirung des Vitamins B,, als Modellsubstanz fiir die dam& (1937) diskutierte Formel des Thiochroms3) Interesse fand. Die Synthesen schlossen vom Imidazol-(2)-thiol(=2-Mercapto-imidazol) aus den Thiazolring4). Die andere Synthese-Moglichkeit, die Kondensation eines 2-Amino-thiazols mit Bromketon, haben H. Kondo und F. Nag a s a was) beniitzt, die das 3-Methyl-6-phenyl-imidazothiazol aus 2-Amino-4-methyl-thiazol und a-Brom-acetophenon in einer Ausbeute von 58 % d.Th. erhalten konnten. EN I 2-A~etamin0-thia~01 w -Bmm-acetophenon Die groDe &dichkeit zwischen Pyridin und Thiazol hat ~N . C O . C H~ uns untersuchen lassen, ob sich w e r e neuen Synthesen des Imidazo -(1.2-a)pyridins auch zum II AHa.CO.C6H, 2-Amino-t?li8zol + w-Br om-eoetophenon e, -1 + o-Brom-uxtophenon l ) 111. Mitteil. iiber Imidazopyridin und verwandte Ringsysteme, 11. Mitteil. 8. F. z, A. M. P a t t e r s o n u. L. T.

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Acylated 2-Iminothiazolines

Cited by 8 publications

References 3 publications

The Chemistry of the Alkali Amides.

The Chemistry of the Alkali Amides.

Aminothiazoles and Their Derivatives

Zur Kenntnis des Imidazothiazol‐Ringsystems

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