2021
DOI: 10.26434/chemrxiv.14157059.v1
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Acylboronates in Polarity-Reversed Generation of Acyl Palladium(II) Intermediates

Abstract: We report a catalytic cross-coupling process between aryl (pseudo)halides and boron-based acyl anion equivalents. This mode of acylboronate reactivity represents polarity reversal, which is supported by the observation of tetracoordinated boronate and acyl palladium(II) species by <sup>11</sup>B, <sup>31</sup>P NMR, and mass spectrometry. A broad scope of aliphatic and aromatic acylboronates has been examined, as well as a variety of aryl (pseudo)halides.

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