Acylcobalt salophen complexes. Homolytic decomposition to salicyl aldehyde esters

Pattenden, Gerald; Tankard, Mark

doi:10.1016/0022-328x(93)83151-k

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Acyl Radicals From Acylcobalt(iii) Derivatives (Rco−col N )2

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Cited by 4 publications

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“…White light photolysis of allyl and arylacetyl cobalt salophens in the presence of diphenyl disulfide, and a number of other traps, provided the expected products of acyl radical formation, decarbonylation, and trapping in moderate to good yield (Scheme ) . Migration of the acyl group from cobalt to the ligand resulting in the isolation of acyl salicyl aldehyde esters was reported to be a problem in certain aliphatic acylcobalt cases …”

Section: Acyl Radicals From Acylcobalt(iii) Derivatives (Rco−col N )mentioning

confidence: 99%

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Chemistry of Acyl Radicals

et al. 1999

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Section: Acyl Radicals From Acylcobalt(iii) Derivatives (Rco−col N )mentioning

confidence: 99%

“…149 Migration of the acyl group from cobalt to the ligand resulting in the isolation of acyl salicyl aldehyde esters was reported to be a problem in certain aliphatic acylcobalt cases. 150…”

Section: Acyl Radicals From Acylcobalt(iii) Derivatives (Rco−col N )mentioning

confidence: 99%