Abstract:2002 stereochemistry stereochemistry (general, optical resolution) O 0030
-030Acylotropic Tautomerism. Part 35. R⇔L-Inversion of Configuration of Dipolar Spirocyclic and Open-Chain 2-Arylaminotropone Isomers.-The R⇔L inversion of the configuration of various spirocyclic arylaminotropone derivatives (I)-(IV) is studied using dynamic NMR technique. Kinetics of the inversion, the dissociation of the spiro bonds and activation energy for torsions are discussed in detail. Compounds (Ia)-(Ic) do not undergo R⇔L inve… Show more
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