Acylseleno- and acylthioureato complexes of gold(i) N-heterocyclic carbenes

Abstract

Gold(i) N-heterocyclic carbene complexes with anionic acylselenourea ligands bound to gold only through selenium were prepared in a one-pot procedure.

Acylselenoureas, selenosemicarbazones and selenocarbamate esters: Versatile ligands in coordination chemistry

“…These include the mono-and dinuclear gold(I) complexes containing phosphines or N-heterocyclic carbene coligands. 73,74 In the X-ray structures of these complexes the acylselenoureato moiety is rotated in such a way, that the hard oxygen atom points away from the soft metal centre. These gold(I)…”

“…These include the mono-and dinuclear gold(I) complexes containing phosphines or N-heterocyclic carbene co-ligands. 73,74 In the X-ray structures of these complexes the acylselenoureato moiety is rotated in such a way, that the hard oxygen atom points away from the soft metal centre. These gold(I) complexes were also amongst the first examples of heteroleptic acylselenourea complexes in which there are additional ligands present in the coordination sphere of the metal.…”

S,O or S,N Coordination? Unraveling the Coordination Modes of Arenesulfonylthiourea Ligands

“…Given our interest in the coordination chemistry of acylthioureas ArC­(O)­NHC­(S)­NR 2 , ,,− we wished to reexamine the behavior of arenesulfonylthioureas with a variety of metals and to study the resulting complexes with modern spectroscopic methods and X-ray diffraction.…”

Crystal structure of tris{N,N-diethyl-N′-[(4-nitrophenyl)(oxo)methyl]carbamimidothioato}cobalt(III)

“…those not involving hydrogen, have negligible coverage.4. Database surveyA search of the Cambridge Structural Database (CSD, version 5.45, update of March 2024;Groom et al, 2016) using a search fragment consisting of just the organic ligand, returned two hits: ZIMNOA(Saeed et al, 2013), a square-planar Ni II complex that contains two of the ligands and NOJWIV(Kuchar et al, 2019), a gold complex that has little else in common with I. A modified search with the NO 2 group replaced by 'any atom' gave 75 matches.…”