The objective of this work is to quantify the systematic errors introduced by the common assumption of invariant secondary electron spectra with changing field sizes, as relevant to stereotactic radiotherapy and other treatment modes incorporating small beam segments delivered with a linacâbased stereotactic unit. The EGSnrc/BEAMnrc Monte Carlo radiation transport code was used to construct a dosimetricallyâmatched model of a Varian 600C linear accelerator with mounted BrainLAB microâmultileaf collimator. Stoppingâpower ratios were calculated for field sizes ranging from 6Ă6âmm2 up to the maximum (98Ă98âmm2), and differences between these and the reference field were computed. Quantitative stopping power data for the BrainLAB microâmultileaf collimator has been compiled. Field size dependent differences to reference conditions increase with decreasing field size and increasing depth, but remain a fraction of a percent for all field sizes studied. However, for dosimetry outside the primary field, errors induced by the assumption of invariant electron spectra can be greater than 1%, increasing with field size. It is also shown that simplification of the SpencerâAttix formulation by ignoring secondary electrons below the cutoff kinetic energy applied to the integration results in underestimation of stoppingâpower ratios of about 0.3% (and is independent of field size and depth). This work is the first to quantify stopping powers from a BrainLAB microâmultileaf collimator. Many earlier studies model simplified beams, ignoring collimator scatter, which is shown to significantly influence the spectrum. Importantly, we have confirmed that the assumption of unchanging electron spectra with varying field sizes is justifiable when performing (typical) inâfield dosimetry of stereotactic fields. Clinicians and physicists undertaking precise outâofâfield measurements for the purposes of risk estimation, ought to be aware that the more pronounced spectral variation results in stopping powers (and hence doses) that differ more than for inâfield dosimetry.PACS number: 87.10.RT; 87.53.Ly; 87.56.jf; 87.56.jk