Addition and NN bond cleavage of diazo-compounds by phosphino-phosphenium cations

Kim, Hyehwang; Lough, Alan; Qu, Zheng-wang; Grimme, Stefan; Stephan, Douglas W.

doi:10.1039/d3cc05728c

Chem. Commun.

2024

DOI: 10.1039/d3cc05728c

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Addition and NN bond cleavage of diazo-compounds by phosphino-phosphenium cations

Hyehwang Kim,

Alan Lough,

Zheng-wang Qu

et al.

Abstract: The phosphino-phosphenium cation (PPC) [Ph3PPPh2][GaCl4] reacts as a frustrated Lewis pair to add across the N=N bond of (tBuO2CN)2. In contrast, photolytical addition [Ph2PClPPh2][GaCl4] to (RN)2 results in cleavage of...

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Structural constraint at a P–P bond: phosphinophosphination of alkenes, alkynes, and carbonyls by a concerted mechanism

You,

Roth,

Greb

2025

Chem. Sci.

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Structural constraint at a P–P bond: phosphinophosphination of alkenes, alkynes, and carbonyls by a concerted mechanism

You,

Roth,

Greb

2025

Chem. Sci.

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show abstract

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Addition and NN bond cleavage of diazo-compounds by phosphino-phosphenium cations

Abstract: The phosphino-phosphenium cation (PPC) [Ph3PPPh2][GaCl4] reacts as a frustrated Lewis pair to add across the N=N bond of (tBuO2CN)2. In contrast, photolytical addition [Ph2PClPPh2][GaCl4] to (RN)2 results in cleavage of...

Cited by 1 publication

References 31 publications

Structural constraint at a P–P bond: phosphinophosphination of alkenes, alkynes, and carbonyls by a concerted mechanism

Structural constraint at a P–P bond: phosphinophosphination of alkenes, alkynes, and carbonyls by a concerted mechanism

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