Addition of 4-phenyl-2-imidazole-2-thione to N-alkyl-1-aza-1,3-enynes

Karpov, M. V.; Davidovich, P. B.; Orlova, D. D.; Belyaev, A. N.; Гарабаджиу, А. В.

doi:10.1134/s1070363215010375

Search citation statements

Order By: Relevance

Paper Sections

Select...

Ftir Spectra1

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2020

2024

Publication Types

Select...

Article2

Relationship

Self Cite0

Independent2

Authors

Journals

Cited by 2 publications

(1 citation statement)

References 5 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Bands at 983 & 960 cm -1 in [6] indicate the presence of cis-MoO 2 2+ core 38 . 39,40 has N-H peak at 13.00 ppm. Since -OH, -NH 2 , -SH are labile protons and spectrum is taken in some solvent, so they have no characteristic chemical shift.…”

Section: Ftir Spectramentioning

confidence: 99%

Reactions of MoCl5 and MoO2Cl2 with 4-Phenylimidazole-2-thiol and 2-Thiazoline-2-thiol

Rani

Singh²,

Sharma³

2020

Orient. J. Chem

View full text Add to dashboard Cite

Reactions of MoCl5/MoO2Cl2 with 4-phenylimidazole-2-thiol/2-thiazoline-2-thiol in CH3CN solvent in 1:1/1:2 molar ratios have been carried out at room temperature. Products obtained MoCl3(C9H7N2S)(CH3CN),[1]; MoCl2(C9H7N2S)(CH3CN), [2]; Mo2OCl4(C9H8N2S)2, [3] and Mo4O2Cl12(C9H7N2S)4, [4]; MoO2Cl3(C3H5NS2)2, [5] and Mo2O4Cl3(C3H5NS2)2, [6] have been analyzed and characterized by elemental analysis, FTIR, 1H NMR and LC-MS techniques. Compounds being moisture and air sensitive, these have been prepared in inert atmosphere using vacuum line and liquid nitrogen cooled traps. Fragments obtained in LC-MS spectra support the formulae derived.

show abstract

Section: Ftir Spectramentioning

confidence: 99%