Addition of a Phosphinoboronate Ester to Borole and Borafluorene

Martin, Caleb D.; Akram, Manjur O.; Vogels, Christopher M.; Santos, Webster L.; Westcott, Stephen A.

doi:10.1055/a-2158-9726

Synlett

2023

DOI: 10.1055/a-2158-9726

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Addition of a Phosphinoboronate Ester to Borole and Borafluorene

Caleb D. Martin,

Manjur O. Akram,

Christopher M. Vogels

et al.

Abstract: The addition of phosphinoboronate ester, Ph2PBpin, with an antiaromatic borole and a borafluorene is reported. The Lewis acid/base adducts are achieved in excellent yields and represent the first P-donor adducts of Ph2PBpin.

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2024

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Synthesis of Phosphinoboranes via Coordination-Induced Bromine Abstraction of an Isolable Phosphinyl Radical with Bromoboranes

Ishida,

Iwamoto,

Katayama

et al. 2024

Synthesis

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A stable dialkylphosphinyl radical reacted with bromoboranes to afford the corresponding phosphinoboranes accompanied with a bromophosphine under neutral condition at room temperature. The obtained phosphinoboranes have almost planar structures and have an effective P–B dative π-bond. The formation of phosphinoboranes would proceed via coordination-induced bromine abstraction from bromoboranes as a pivotal step, which was supported by the computational study.

show abstract

Synthesis of Phosphinoboranes via Coordination-Induced Bromine Abstraction of an Isolable Phosphinyl Radical with Bromoboranes

Ishida,

Iwamoto,

Katayama

et al. 2024

Synthesis

View full text Add to dashboard Cite

show abstract

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Addition of a Phosphinoboronate Ester to Borole and Borafluorene

Abstract: The addition of phosphinoboronate ester, Ph2PBpin, with an antiaromatic borole and a borafluorene is reported. The Lewis acid/base adducts are achieved in excellent yields and represent the first P-donor adducts of Ph2PBpin.

Cited by 1 publication

References 58 publications

Synthesis of Phosphinoboranes via Coordination-Induced Bromine Abstraction of an Isolable Phosphinyl Radical with Bromoboranes

Synthesis of Phosphinoboranes via Coordination-Induced Bromine Abstraction of an Isolable Phosphinyl Radical with Bromoboranes

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