Additions and corrections

Ferrari, Marisa Belicchi; Fava, Giovanna Gasparri; Pelizzi, Corrado; Tarasconi, Pieralberto

doi:10.1039/dt9920003163

Cited by 29 publications

(55 citation statements)

References 0 publications

Supporting

Mentioning

Contrasting

Unclassified

Order By: Relevance

“…The shortest distance is slightly longer than those found in other copper() complexes with thiosemicarbazone ligands and chloro bridges [25] and the longest distance is in the range found in other systems with chloro bridges between copper centers (2.70-3.19 Å). [31,32] In 6a both Cu-Br bond lengths are also significantly different.…”

Section: Resultsmentioning

confidence: 76%

“…The formation of dimers is not unusual in copper() complexes of thiosemicarbazones. [4,25] However, the majority of such compounds have the formula [Cu(L)Cl] 2 , where the bridging atom is either the sulfur or the chlorine atom, which gives rise to a coordination number of five around the metal center. In the case where L is 2-pyridinecarboxaldehyde thiosemicarbazone it was possible to obtain both structures, [4] each with a pyramidal geometry; that is, the copper() centers are joined either by two thiolate bridges from the thiosemicarbazone or by two chloro bridges.…”

Section: Resultsmentioning

confidence: 99%

See 1 more Smart Citation

Synthesis, Characterization, and Properties of Some Copper(II) Complexes of 2‐Pyridineformamide Thiosemicarbazone (HAm4DH)

et al. 2006

View full text Add to dashboard Cite

Reactions between different copper(II) salts and 2-pyridineformamide thiosemicarbazone (HAm4DH) in neutral ethanolic media led to the formation of complexes with the formulae [Cu(HAm4DH)X 2 ] (X = Cl or Br) (1, 2) and [Cu-(HAm4DH) 2 ]X 2 (X = NO 3 or ClO 4 ) (3, 4). The same reactions carried out in the presence of triethylamine gave rise to new complexes with the general formulae [Cu(Am4DH)X] (X = Cl, Br, AcO, or NO 3 ) (5-8), [Cu(H 2 O)(Am4DH)](ClO 4 ) (9), and [Cu(Am4DH) 2 ] (10), many of which were isolated with different molecules of crystallization and contain a deprotonated thiosemicarbazone (Am4DH). These complexes were characterized by elemental analysis, and different spectroscopic and magnetic techniques. The thermal and redox behavior of the complexes was also evaluated. Complexes 1, 2,

show abstract

Section: Resultsmentioning

confidence: 76%

Section: Resultsmentioning

confidence: 99%

Synthesis, Characterization, and Properties of Some Copper(II) Complexes of 2‐Pyridineformamide Thiosemicarbazone (HAm4DH)

et al. 2006

View full text Add to dashboard Cite

show abstract

“…Fe III [23], Co III [24] and Ni II [25], when an octahedral coordination mode is preferred. In case of Cu II mainly mono-ligand complexes were described [11,26,27] sometimes in dimerized form [13]. The on erythroleukemia cell erythroid differentiation, although in both cases the monomeric forms were assumed to be the active species [27].…”

Section: Introductionmentioning

confidence: 99%

“…Bis-ligand complexes are formed with e.g. Fe III [23], Co III [24] and Ni II [25], when an octahedral coordination mode is preferred. In case of Cu II mainly mono-ligand complexes were described [11,26,27] sometimes in dimerized form [13].…”

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Complexes of pyridoxal thiosemicarbazones formed with vanadium(IV/V) and copper(II): Solution equilibrium and structure

Jakusch

Kozma

Enyedy

et al. 2018

Inorganica Chimica Acta

View full text Add to dashboard Cite

show abstract

Neue ONS-Liganden und ihre Zinkkomplexe mit Bezug zum Zinkenzym Alkoholdehydrogenase

Sudbrake

Vahrenkamp

2001

Z. anorg. allg. Chem.

View full text Add to dashboard Cite

Professor Kurt Dehnicke zum 70. Geburtstag gewidmet Inhaltsu È bersicht. Durch Ringo È ffnung von Dimethylthiiran mit Ethanolamin bzw. durch Schiffbasen-Kondensation von Salicylaldehyden mit 2-Mercaptoisobutylamin wurden die dreiza Èhnigen ONS-Liganden H 2 MIEA, H 2 MIIMP und H 2 MIIMTP gewonnen. Ersterer lieferte den Zinkkomplex (MIEA)Zn-(Ethanolamin) (1) mit trigonal-bipyramidaler ZnO 2 N 2 S-Koordination. Letztere ergaben mit Zn[N(SiMe 3 ) 2 ] 2 die vermutlich dimeren Komplexe Zn(MIIMP) und Zn(MIIMTP) (2 a, b). Benzoylpyridin und Phenylhydroxymethylpyridin als zweiza È hnige Koliganden L lieûen sich mit H 2 MIIMP zu den Komplexen L´Zn(MIIMP) (3, 4) kombinieren, deren ZnO 2 N 2 S-Koordination der von 1 entspricht. Partielle hydrolytische Zersetzung fu È hrte zu dem ungewo È hnlichen Dreikernkomplex 5, der u. a. das Kondensationsprodukt des Salicylaldimins mit Benzoylpyridin als Ligand entha È lt. Die erhaltenen Komplexe und die beobachteten Koordinationsmuster repra È sentieren neue strukturelle Analogien zur Umgebung des Zinks im Enzym Pferdeleber-Alkoholdehydrogenase. New ONS Ligands and their Zinc Complexes with Relation to the Zinc Enzyme AlcoholdehydrogenaseAbstract. By ring opening of dimethyl thiirane with ethanolamine or by Schiff base condensation between salicylic aldehydes and 2-mercaptoisobutylamine the tridentate ONS ligands H 2 MIEA, H 2 MIIMP, and H 2 MIIMTP were obtained. The former yielded the zinc complex (MIEA)Zn(ethanolamine) (1) with a trigonal bipyramidal ZnO 2 N 2 S coordination. The latter two and Zn[N(SiMe 3 ) 2 ] 2 yielded the presumably dimeric complexes Zn(MIIMP) and Zn(MIIMTP) (2 a, b). Benzoyl pyridine and phenylhydroxymethylpyridine as bidentate coligands L could be combined with H 2 MIIMP in the complexes L´Zn(MIIMP) (3, 4) whose ZnO 2 N 2 S coordination corresponds to that of 1. Partial hydrolytic degradation led to the unusual trinuclear complex 5 which contains, inter alia, the condensation product of the salicylic aldimine and benzoyl pyridine as a ligand. The complexes obtained and the coordination patterns observed represent new structural analogies with the environment of zinc in the enzyme horse liver alcoholdehydrogenase.

show abstract

Additions and corrections

Abstract: The last three bond angles of compound 3 should be replaced with N(3)-Zn-O( 1) 86.8( 1) S-Zn-O( 1) 135.9( 1) N ( 3)-2 n-C 1'

Cited by 29 publications

References 0 publications

Synthesis, Characterization, and Properties of Some Copper(II) Complexes of 2‐Pyridineformamide Thiosemicarbazone (HAm4DH)

Synthesis, Characterization, and Properties of Some Copper(II) Complexes of 2‐Pyridineformamide Thiosemicarbazone (HAm4DH)

Complexes of pyridoxal thiosemicarbazones formed with vanadium(IV/V) and copper(II): Solution equilibrium and structure

Neue ONS-Liganden und ihre Zinkkomplexe mit Bezug zum Zinkenzym Alkoholdehydrogenase

Contact Info

Product

Resources

About