2018
DOI: 10.1021/acs.biomac.8b01318
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Admicellar Polymerization Coating of CNF Enhances Integration in Degradable Nanocomposites

Abstract: A water-based one-pot synthesis strategy for converting cellulose nanofibrils (CNF) into a hydrophobic and processable biopolymer grade is devised. CNF was chemically modified through admicellar polymerization, producing fibrils coated with fatty acrylate polymers. The proposed modification targets a change in the interfibrillar interactions and improved CNF compatibility with a degradable plastic composite matrix, poly(butylene adipate-co-terephthalate), PBAT in composites prepared by melt extrusion. CNF had … Show more

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Cited by 21 publications
(17 citation statements)
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“…This leaves a small amount of non-resorbable cellulose-based material [164]. With periodate oxidation, many recent types of research have attempted to enhance the biodegradability in vitro [165]. Various micro-organisms use cellulose as a carbon source; hence, they degrade it with specific enzymes, but not on an in vivo scale.…”
Section: Biodegradabilitymentioning
confidence: 99%
“…This leaves a small amount of non-resorbable cellulose-based material [164]. With periodate oxidation, many recent types of research have attempted to enhance the biodegradability in vitro [165]. Various micro-organisms use cellulose as a carbon source; hence, they degrade it with specific enzymes, but not on an in vivo scale.…”
Section: Biodegradabilitymentioning
confidence: 99%
“…In recent decades, the use of fossil fuel-based plastics has produced production and waste management problems. These products are low cost, [1,2] versatile and highly resistant to heat, humidity, sunlight, and microbial contamination. [3,4] These properties provide the materials with attractive mechanical, thermal and barrier properties.…”
Section: Introductionmentioning
confidence: 99%
“…Polymeric films attract a significant degree of interest because of their widespread use in several industrial applications, with particular reference to packaging. Over the last decades, the large use of oil-derived polymers, due to their good mechanical, thermal and barrier properties, as well as their low cost, has led to significant problems in term of production and accumulation of wastes [1,2]. Rising concern about the reduction of waste coming from plastic packaging has encouraged both academia and industry to engage in research focused on polymers coming from natural resources, biodegradable or compostable [3,4,5,6].…”
Section: Introductionmentioning
confidence: 99%