This paper deals with a novel adsorbed phase ozonation process that enhances the reaction rate between ozone and organic pollutants, especially focusing on their reaction kinetics on ZSM-5s. In this study, we elucidated that adsorptive concentrations in ozone and organic chemical were dominant factors for the increases in reaction rate, and developed a novel method for predicting the reaction rates between ozone and organic chemical on ZSM-5s.