Adsorption and deposition-assisted anodic stripping voltammetry for determination of antimony(III) in presence of hematoxylin on glassy carbon electrode

In this study, we introduce a very sensitive and selective method for the differential pulse anodic stripping determination of Sb(III) ion on the over‐oxidized poly(phenol red) modified glassy carbon electrode (PPhRedox/GCE) in 0.1 mol L‐1 HCl medium. The formation of both poly(phenol red) and over‐oxidized poly(phenol red) film on the electrode surfaces were characterized by electrochemical impedance spectroscopy, X‐ray photoelectron spectroscopy and scanning electron microscopy techniques. An anodic stripping peak of Sb(III) was observed at 0.015 V on the PPhRedox/GCE. Higher anodic stripping peak current of Sb(III) was obtained at PPhRedox/GCE compared with both bare GCE and poly(phenol red) film modified GCE (PPhRed/GCE). The calibration graph consisted of two linear segments of 0.044 ‐ 1.218 μg L−1 and 3.40 – 18.26 μg L−1 with a detection limit of 0.0075 μg L−1. The proposed over‐oxidized polymer film modified electrode was applied successfully for the analysis of antimony in different spiked water samples. Spiked recoveries for water samples were obtained in the range of 93.0–103.0%. The accuracy of the method was also verified through the analysis of standard reference materials (SCP SCIENCE‐EnviroMAT™ EP−L‐2).

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Over‐Oxidized Poly (Phenol Red) Film Modified Glassy Carbon Electrode for Anodic Stripping Voltammetric Determination of Ultra‐Trace Antimony (III)

Karabiberoğlu

Dursun

2016

Electroanalysis

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Speciation of antimony in anti-leishmanial drug using two different chemical receptors and adsorptive anodic stripping voltammetry on glassy carbon electrode

2021

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A highly selective electrochemical sensor for trace determination and speciation of antimony (III & V) in water and soil samples using 2-thenoyltrifluoroacetone

et al. 2020

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Adsorption and deposition-assisted anodic stripping voltammetry for determination of antimony(III) in presence of hematoxylin on glassy carbon electrode

Cited by 12 publications

References 34 publications

Over‐Oxidized Poly (Phenol Red) Film Modified Glassy Carbon Electrode for Anodic Stripping Voltammetric Determination of Ultra‐Trace Antimony (III)

Over‐Oxidized Poly (Phenol Red) Film Modified Glassy Carbon Electrode for Anodic Stripping Voltammetric Determination of Ultra‐Trace Antimony (III)

Speciation of antimony in anti-leishmanial drug using two different chemical receptors and adsorptive anodic stripping voltammetry on glassy carbon electrode

A highly selective electrochemical sensor for trace determination and speciation of antimony (III & V) in water and soil samples using 2-thenoyltrifluoroacetone

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