2002
DOI: 10.1006/jcis.2002.8411
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Adsorption and Isotope Effects by Ion Exchange with Aqueous-2-Aminomethyl-18-Crown-6 Bonded Merrifield Resin

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Cited by 5 publications
(2 citation statements)
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“…The simplest interpretation of these experiments is that the fractionation of magnesium isotopes occurs in growth of the cyanobacteria and synthesis of chlorophyll- The step that causes fractionation in chlorophyll synthesis is unknown, but we suspect that it is related to a chelation step, since it is well documented that chelation can cause fractionation of magnesium isotopes on resins (Chang et al, 2003;Kim et al, 2002;2003;Kim and Kang, 2001). The precise mechanism for insertion of magnesium into the tetrapyrrole ring (protoporphyrin IX, Figure 1) during the biosynthesis of chlorophyll is not known.…”
Section: Discussionmentioning
confidence: 99%
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“…The simplest interpretation of these experiments is that the fractionation of magnesium isotopes occurs in growth of the cyanobacteria and synthesis of chlorophyll- The step that causes fractionation in chlorophyll synthesis is unknown, but we suspect that it is related to a chelation step, since it is well documented that chelation can cause fractionation of magnesium isotopes on resins (Chang et al, 2003;Kim et al, 2002;2003;Kim and Kang, 2001). The precise mechanism for insertion of magnesium into the tetrapyrrole ring (protoporphyrin IX, Figure 1) during the biosynthesis of chlorophyll is not known.…”
Section: Discussionmentioning
confidence: 99%
“…Similar chelating resins and magnesium-binding molecules are known to induce an isotopic fractionation in purely inorganic systems (e.g. 26 Mg enrichment on functionalized Merrifield peptide resins, Kim and Kang, 2001;Kim et al, 2002Kim et al, , 2003.…”
Section: Introductionmentioning
confidence: 99%