Adsorption and recovery of lithium ions from groundwater using date pits impregnated with cellulose nanocrystals and ionic liquid

Wahib, Sara A.; Da’na, Dana A.; Zaouri, Nabil; Hijji, Yousef M.; Al-Ghouti, Mohammad A.

doi:10.1016/j.jhazmat.2021.126657

Cited by 39 publications

(6 citation statements)

References 78 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Te data obtained from Fe was ftted to the Freundlich isotherm model and indicated that the adsorption sites were uneven and nonspecifc. Wahib et al [229] aims to produce an adsorbent using date pits (DP) impregnated with CNCs and ionic liquid (IL) called IL-CNC/DP. According to general observations, the Dubinin-Radushkevich isotherm is the best-ftting isotherm model for Li(I) adsorption based on R 2 .…”

Section: Pseudo-second Ordermentioning

confidence: 99%

Cellulose Nanocrystals (CNCs) and Cellulose Nanofibers (CNFs) as Adsorbents of Heavy Metal Ions

Kurniawan

Sulistyarti

Rumhayati

et al. 2023

Journal of Chemistry

View full text Add to dashboard Cite

The isolation of nanocellulose has been extensively investigated due to the growing demand for sustainable green materials. Cellulose nanocrystals (CNCs) and cellulose nanofibers (CNFs), which have the same chemical composition but have different morphology, particle size, crystallinity, and other properties depending on the precursor and the synthesis method used. In comparison, CNC particles have a short rod-like shape and have smaller particle dimensions when compared to CNF particles in the form of fibers. CNC synthesis was carried out chemically (hydrolysis method), and CNF synthesis was carried out mechanically (homogenization, ball milling, and grinding), and both can be modified because they have a large surface area and are rich in hydroxyl groups. Modifications were made to increase the adsorption ability of heavy metal ions. The Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermogravimetric (TG), and dynamic light scattering (DLS) can reveal the characteristics and morphology of CNCs and CNFs. The success and effectiveness of the heavy metal adsorption process are influenced by a few factors. These factors include adsorbent chemical structure changes, adsorbent surface area, the availability of active sites on the adsorbent’s surface, adsorption constants, heavy metal ionic size differences, pH, temperature, adsorbent dosage, and contact time during the adsorption process. In this review, we will discuss the characteristics of CNCs and CNFs synthesized from various precursors and methods, the modification methods, and the application of CNCs and CNFs as heavy metal ion adsorbents, which includes suitable isotherm and kinetics models and the effect of pH on the selectivity of various types of heavy metal ions.

show abstract

Section: Pseudo-second Ordermentioning

confidence: 99%

Cellulose Nanocrystals (CNCs) and Cellulose Nanofibers (CNFs) as Adsorbents of Heavy Metal Ions

Kurniawan

Sulistyarti

Rumhayati

et al. 2023

Journal of Chemistry

View full text Add to dashboard Cite

show abstract

“…Nanocellulose has frequently been chemically modified to increase its adsorption property for Li ions. For example, Wahib [ 87 ] impregnated date pits with cellulose nanocrystals with the presence of ionic liquid of 3‐formyl‐1‐methyl pyridinium iodide. The adsorbent presented a Li + uptake of 99 mg g −1 at a concentration of 100 mg L −1 due to the existence of electrostatic interactions and H‐bonding between Li + and less protonated adsorbent surface.…”

Section: Extraction Of Battery‐related Metals With Biofibrous Nanomat...mentioning

confidence: 99%

Biofibrous nanomaterials for extracting strategic metal ions from water

et al. 2022

View full text Add to dashboard Cite

Strategic metals play an indispensable role in the related industries. Their extraction and recovery from water are of great significance due to both their rapid consumption and environmental concern. Biofibrous nanomaterials have shown great advantages in capturing metal ions from water. Recent progress in extraction of typical strategic metal ions such as noble metal ions, nuclear metal ions, and Li-battery related metal ions is reviewed here using typical biological nanofibrils like cellulose nanofibrils, chitin nanofibrils, and protein nanofibrils, as well as their assembly forms like fibers, aerogels/hydrogels, and membranes. An overview of advances in material design and preparation, extraction mechanism, dynamics/thermodynamics, and performance improvement in the last decade is provided. And at last, we propose the current challenges and future perspectives for promoting biological nanofibrous materials toward extracting strategic metal ions in practical conditions of natural seawater, brine, and wastewater.

show abstract

“…Previous reports have shown that iridescent PVA composite films can be fabricated with the combination of CNCs and ionic liquids [ 12 ]. This composite is of high strength and toughness [ 13 ] and can adsorb and recover lithium ions from groundwater [ 14 ]. These works reveal that CNCs and ionic liquid could be homogenized in one functioning composite.…”

Section: Introductionmentioning

confidence: 99%

Synergistic Effects of 1-Octyl-3-Methylimidazolium Hexafluorophosphate and Cellulose Nanocrystals on Improving Polyacrylate Waterborne Anti-Corrosion Coatings

Wang

2023

Polymers

View full text Add to dashboard Cite

In this study, three copolymers of poly(methyl methacrylate) and poly(butyl acrylate) (PMMA-co-PBA) latex containing 1-octyl-3 methylimidazolium hexafluorophosphate (C8mimPF6), cellulose nanocrystals (CNCs), and C8mimPF6-CNCs were successfully synthesized through mini emulsion polymerization. These novel composites were each coated on mild steel panels and tested for their anti-corrosion performance by immersion of the coated samples in 3.5 wt% sodium chloride (NaCl) solution over a certain period. The synergistic anti-corrosion effects of the C8mimPF6-CNCs sample led to the highest coating resistance, charge transfer resistance, and corrosion inhibition efficiency and the lowest diffusion coefficient and corrosion rate. The proposed synergistic mechanism revealed that CNCs enhanced the barrier effect of the coating while C8mimPF6 inhibited corrosion when released.

show abstract

Adsorption and recovery of lithium ions from groundwater using date pits impregnated with cellulose nanocrystals and ionic liquid

Cited by 39 publications

References 78 publications

Cellulose Nanocrystals (CNCs) and Cellulose Nanofibers (CNFs) as Adsorbents of Heavy Metal Ions

Cellulose Nanocrystals (CNCs) and Cellulose Nanofibers (CNFs) as Adsorbents of Heavy Metal Ions

Biofibrous nanomaterials for extracting strategic metal ions from water

Synergistic Effects of 1-Octyl-3-Methylimidazolium Hexafluorophosphate and Cellulose Nanocrystals on Improving Polyacrylate Waterborne Anti-Corrosion Coatings

Contact Info

Product

Resources

About