Adsorption and Structural Properties of Heteropolyacid-modified Pd/AI2O3 Catalysts: Effects on Hydrogenation Activity

Volkova, L. D.; Zakarina, N. A.; Artyukhina, Galina V.; Kul'evskaya, Y. G.

doi:10.1070/mc1994v004n03abeh000372

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2019

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“…Also, because of the higher loading of Pd in Pd/MCM‐41, the formation of palladium black is visible during the reaction. The found observations are in good agreement with the reported ones, , …”

Section: Resultssupporting

confidence: 93%

Hydrogenation of Cyclohexene in Aqueous Solvent Mixture Over a Sustainable Recyclable Catalyst Comprising Palladium and Monolacunary Silicotungstate Anchored to MCM‐41

Patel

Narkhede

2019

Eur J Inorg Chem

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An efficient, highly stable, and ligand-free catalyst consisting of Pd and monolacunary silicotungstate anchored to MCM-41 was synthesized and characterized by various techniques. The synthesized catalyst was used for the hydrogenation reaction of cyclohexene as model substrate, and various reaction parameters were studied in order to optimize them for maximum conversion, 95 %, under mild conditions. The catalyst [a]

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Section: Resultssupporting

confidence: 93%