Adsorption and Visualization of Solvated Na/Br Carbenoids on Ag(111)
Barbara Pieczyrak,
Abhijit Bera,
Katharina Dilchert
et al.
Abstract:The solvent tetrahydrofuran (THF) stabilizes Na/Br carbenoids in the liquid phase. We investigate the importance of the THF solvent upon Na/Br carbenoid adsorption on Ag(111) using density functional theory and scanning tunneling microscopy. The three-dimensional structure of the Na/Br carbenoid is maintained upon surface adsorption. A second solvation shell of molecules surrounds it. Whether or not additional THF molecules, calculated to stabilize the Na of the Na/Br carbenoid in the gas phase, are liberated … Show more
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