The adsorption capacity of adsorbent materials at low relative pressure range is a crucial parameter that guarantee the high overall performance and efficiency of adsorption cooling and water desalination systems. MIL-101(Cr) is a metal-organic framework (MOF) material with a high-water vapour uptake of 1.36-1.47 g 2 H O g ads-1. However, MIL-101(Cr) exhibits an IV isotherm (S-shaped isotherm) which means that the high-water uptake only takes place at high relative pressure (≥ 0.5). This drawback makes MIL-101(Cr) impractical for adsorption applications working at lower relative pressure such as adsorption cooling and desalination with cooling effect which operate at relative pressures ≤0.4. In this work, MIL-101(Cr)/CaCl 2 composites were synthesized, the unsupported and CaCl 2 supported materials were fully characterized in terms of their structure (XRD), thermal stability, vibrational spectroscopy structure, morphology (SEM), water adsorption capacity and BET surface area. As a result, incorporating CaCl 2 into the MIL-101(Cr) structure significantly enhanced water adsorption characteristics in the desired relative pressure range as the water vapour uptake for Comp_1:8 CaCl 2 composite increasing from only 0.1 g 2 H O g ads-1 for as-synthesized MIL-101(Cr) to 0.65 g 2 H O g ads-1 at a relative pressure of 0.3.