2006
DOI: 10.1016/j.colsurfa.2005.07.019
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Adsorption of toluene on Si(1 0 0)/SiO2 substrate and mesoporous SBA-15

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Cited by 33 publications
(28 citation statements)
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“…The SBA-15 silica vector (SBA-15-2) was synthesized using P123 as the structure-directing agent with the reactant molar ratios: 0.017-P123j1.0-TEOSj6.0-HClj196.0-H 2 O (Mirji et al, 2006). In a typical preparation, P123 was dissolved in a mixture of water and HCl (2 M) with stirring for 2 h, after which, TEOS was added, and the system stirred at room temperature for a further 20 h. The resulting gel was then aged (373 K, 48 h).…”
Section: Synthesismentioning
confidence: 99%
“…The SBA-15 silica vector (SBA-15-2) was synthesized using P123 as the structure-directing agent with the reactant molar ratios: 0.017-P123j1.0-TEOSj6.0-HClj196.0-H 2 O (Mirji et al, 2006). In a typical preparation, P123 was dissolved in a mixture of water and HCl (2 M) with stirring for 2 h, after which, TEOS was added, and the system stirred at room temperature for a further 20 h. The resulting gel was then aged (373 K, 48 h).…”
Section: Synthesismentioning
confidence: 99%
“…The new bands appear in the spectra after toluene adsorption. Bands at 3032, 1603 and 1496 cm À1 are attributed to the C-H stretching modes of the aromatic ring and skeleton vibrations of the aromatic ring [42,43], while bands at 1461 and 1384 cm À1 are associated to the asymmetric and symmetric bending modes of the methyl group. Features at 2959, 2928 and 2881 cm À1 are associated to C-H modes of the methyl group.…”
Section: Ft-ir Analysismentioning
confidence: 98%
“…According to literature data, toluene itself is capable of adsorbing on the surface of silicon, giving rise to increase of the contact angle of a water drop on toluene-covered Si(1 0 0)/SiO 2 surface to 528 after 1 h and 698 after 23 h [12]. Therefore, in the first step of this study, adsorption of pure toluene on Si(1 1 1)/SiO 2 surface (as used for the subsequent NR experiments) was investigated.…”
Section: Adsorption On Bare Silicon Surfacementioning
confidence: 98%