Adsorption performance and modelling of malachite green dye removal from aqueous solution using sulphuric acid–modified Ipomoea pes caprae biomass

Saravanan, A.; Yaashikaa, P. R.; Kumar, P. Senthil; Yuvaraj, D.; Karishma, S.; Muthu, C. M. Mathan; Nasrin, M. R. Thasleema; Sree, G. Aarthi; Karthik, V.; Natrayan, L.; Rangasamy, Gayathri

doi:10.1007/s13399-023-05067-y

Cited by 3 publications

(1 citation statement)

References 42 publications

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“…Recently, researchers have extensively applied this model in kinetic studies for various adsorption systems. These systems include the removal of malachite green using DOI: 10.15826/chimtech.2024.11.2.02 oil palm trunk fiber, lead adsorption from aqueous solutions using peat moss, and methylene blue adsorption using broad bean peels [39,[46][47][48].…”

Section: Pseudo First Order Kinetic Modelmentioning

confidence: 99%

A review on agrowaste based activated carbons for pollutant removal in wastewater systems

Okiy,

Tagbo,

Echeng

2024

Chim.Tech.Acta

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Environmental pollution from chemicals utilized in manufacturing, pharmaceuticals, and chemical process industries is of serious concern nowadays due to the contamination that ensues when these chemicals are discharged into water bodies. Activated carbon adsorption provides an efficient and economically viable means for mitigation of toxic chemicals (i.e., heavy metals, dyes, pharmaceutics, and antibiotics). However, the exorbitant cost of commercial activated carbons has resulted in the search for low-cost alternatives for the treatment of contaminated effluents. An exhaustive literature survey in this area is necessary to know the extent of work done in this area and seek out the gaps that future research will provide answers to. In this review, various works on activated carbon utilization, batch adsorption, fixed-bed adsorption (experimental and numerical studies) are summarized. This review elucidates the different kinetic and isotherm models of agrowastes-derived activated carbon materials in context with pollutants (dyes, heavy metals, pharmaceuticals, miscellaneous adsorbates) removal through batch and column methods. In addition, fixed-bed column adsorption/regeneration methods using various activated carbons derived from agrowastes are discussed. Among these methods, heavy metal adsorption from aqueous solutions by the activated carbons is the most efficient. The deployment of mathematical and machine learning approaches (ANN and novel GMDH algorithms) in optimization of batch and continuous adsorption processes are also highlighted. Numerical simulation of fixed-column adsorption systems for more improved industrial-scale column designs is described. Conclusions and future challenges of chemicals removal from polluted wastewater utilizing agrowaste-derived activated carbons are also presented.

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Section: Pseudo First Order Kinetic Modelmentioning

confidence: 99%

A review on agrowaste based activated carbons for pollutant removal in wastewater systems

Okiy,

Tagbo,

Echeng

2024

Chim.Tech.Acta

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Recent trends in biosorption: the removal of emerging dye pollutants from aqueous medium

Boussaksou,

Aoulad El Hadj Ali,

Azzouz

et al. 2024

Euro-Mediterr J Environ Integr

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Artificial neural network modeling of dye adsorption kinetics and thermodynamics with magnetic nanoparticle-activated carbon from Allium cepa peels

Deivayanai,

Karishma,

Thamarai

et al. 2024

Preprint

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The study utilizes novel onion peel (Allium cepa) activated carbon biomass impregnated with magnetic nanoparticles (OMNPs) for the removal of toxic Methylene Blue (MB) and Congo Red (CR) dyes. The SEM analysis reveals the morphological structures, while XRD indicates an amorphous nature. FTIR confirms the functional groups present, TGA demonstrates thermal stability, and the pore size is measured at 2.193 nm. OMNPs reveal a higher sorption rate for both MB and CR dye, with a clearance rate of 96.25% and 93.11%. The thermodynamic reaction is believed to be an exothermic reaction and the process is spontaneous. The simulation investigations indicate that Freundlich is the best-proven isotherm (R2 for MB = 0.9945 and CR dyes = 0.9878), pseudo-second-order kinetics yields chemisorption and ANN is assessed for its fitness (R for MB = 0.993 and CR dyes = 0.984). This new composite material demonstrated remarkable dye removal efficiency, and ANN models accurately predicted adsorption performance.

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Adsorption performance and modelling of malachite green dye removal from aqueous solution using sulphuric acid–modified Ipomoea pes caprae biomass

Cited by 3 publications

References 42 publications

A review on agrowaste based activated carbons for pollutant removal in wastewater systems

A review on agrowaste based activated carbons for pollutant removal in wastewater systems

Recent trends in biosorption: the removal of emerging dye pollutants from aqueous medium

Artificial neural network modeling of dye adsorption kinetics and thermodynamics with magnetic nanoparticle-activated carbon from Allium cepa peels

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