Adsorptive desulfurization using different passivated carbon nanoparticles by PEG-200

Fallah, Rahimeh Naviri; Azizian, Saeid; Dwivedi, Amarendra Dhar; Sillanpää, Mika

doi:10.1016/j.fuproc.2014.10.018

Cited by 25 publications

(12 citation statements)

References 35 publications

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“…Hence, the synthesized catalyst showed a potent effect on the desulfurization of the model diesel fuel, while the FTIR analysis of the catalyst before and after the reactions showed that the mode of desulphurization employed by the catalyst was adsorptive desulfurization. The extent of desulfurization recorded by this work compares closely with the work of Fallah et al (2015), who reported using a different approach.…”

Section: Desulfurization Of Model Dieselsupporting

confidence: 87%

Microwave-Assisted Adsorptive Desulfurization of Model Diesel Fuel Using Synthesized Microporous Rare Earth Metal-Doped Zeolite Y

et al. 2015

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The microwave-assisted adsorptive desulfurization of model fuel (thiophene in n-heptane) was investigated using a synthesized rare earth metal-doped zeolite Y (RE Y). Crystallinity of the synthesized zeolite was 89.5%, the silicon/aluminium (Si/Al) molar ratio was 5.2, the Brunauer–Emmett–Teller (BET) surface area was 980.9 m2/g, and the pore volume and diameter was 0.3494 cm3/g and 1.425 nm, respectively. The results showed that the microwave reactor could be used to enhance the adsorptive desulfurization process with best efficiency of 75% at reaction conditions of 100 °C and 15 minutes. The high desulfurization effect was likely due to the higher efficiency impact of microwave energy in the interaction between sulfur in thiophene and HO-La(OSiAl).

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Section: Desulfurization Of Model Dieselsupporting

confidence: 87%

Microwave-Assisted Adsorptive Desulfurization of Model Diesel Fuel Using Synthesized Microporous Rare Earth Metal-Doped Zeolite Y

et al. 2015

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“…As an effective alternative way, adsorptive desulfurization (ADS) have been modified to capture the sulfur content of fuels to meet the restrict recent limitations of lower than 1.0 ppm using diverse kind of adsorbents such as porous carbons derived from hydrothermal process of sucrose carbonization for the removal of thiophenic compounds, Nitrogen‐doped carbons (NCs) for the removal of 4,6‐dimethyldibenzothiophene, zeolites in selectively capturing aromatic sulfur compounds, porous silica coated on CuO‐modified SBA‐15 applied to the adsorption of CO and metal‐organic frameworks such as HKUST‐1 and CPO‐27‐Ni with high selectivity toward a multipart mixture of aromatics, paraffins, olefins, and naphthenes . Numerous advantages have been reported for ADS such as high efficiency, good selectivity, regenerability, low cost and operations in safe mode and good market prospect …”

Section: Introductionmentioning

confidence: 99%

Experimental and Computational Study of Organic Sulfur Removal Proficiency of (Ni, Cu, Co)‐Doped ZIF‐8 Adsorbents

Saeedirad

Ganjali

Rashidi³

et al. 2020

ChemistrySelect

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The synthesis and characterization of a series of metal‐doped ZIF‐8 (metal=Ni, Co and Cu) has been introduced to gain the highly efficient adsorption of dibenzothiophene (DBT) in liquid phase. Under 150 ml DBT/iso‐octane, 100–1700 ppm, and 25–85 °C, the excellent efficiency and reusability in DBT removal was achieved and fitted better with the pseudo‐first order reaction. The maximum adsorption of 191.84 mg S/g for Ni/ZIF‐8 and two steps for intraparticle diffusion study contrary to Cu‐ and Co‐ZIF‐8 suggested the presence of Ni‐HMeIM clusters in ZIF‐8 cavities. Comparing the performance of prepared adsorbents, the order of qmax and PC was the same, i. e. PC Ni/ZIF‐8> PC Cu/ZIF‐8>PC Co/ZIF‐8>PC ZIF‐8 and qmax (Ni/ZIF‐8)> qmax (Cu/ZIF‐8)> qmax (Co/ZIF‐8)> qmax (ZIF‐8) for both 10% and 100% BT. The prepared adsorbents had the FoMs ranging from 0.05‐0.07 that compared to other adsorbents showed the beneficial use for large scale desulfurization process. The endothermic behavior and a homogeneous adsorption was then indicated through thermodynamic and equilibrium studies.

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“…In addition, HDS is difficult to remove heterocyclic organosulfur such as benzothiophene (BT), dibenzothiophene (DBT) and their derivatives. Due to these reasons, many groups [7][8][9][10] have been engaged in the exploitation of non-HDS technologies for transportation fuels, including extraction [11][12] , oxidation [13][14] , adsorption [15][16] , biological desulfurization [17][18] and others [19][20] .…”

Section: Introductionmentioning

confidence: 99%

Green Carboxylic Acid-Based Deep Eutectic Solvents as Solvents for Extractive Desulfurization

et al. 2016

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The extractive desulfurization of thiophene (TS), dibenzothiophene (DBT), and benzothiophene (BT) in model oil was carried out using carboxylic acid-based deep eutectic solvents (DES). It was found that DES formed by formic acid as hydrogen bond donor and Tetrabutylammonium bromide (TBAB) as hydrogen bond acceptor could efficiently separate organosulfur from oils. The influence parameters in this process were discussed, such as extraction temperature, reaction time, mass ratio of DES to oil; multistage extraction effect; recycle times and regeneration of DES. The results showed that the desulfurization selectivity of TBAB/HCOOH followed the order TS < BT ≈DBT. Under the Optimized conditions, the sulfur removal of BT, DBT and TS were 81.75%, 80.47% and 72% in a single stage, respectively, and after three cycles, it will rise to 98.32%, 98.24% and 97.6%. The sulfur content in fuels can be achieved to less than 8.4, 8.8 and 12 ppm for BT, DBT and TS. In addition, by mechanism discussion, it was proved that hydrogen bonding between the sulfide and DES was the main driving force of the extraction desulfurization process.

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Adsorptive desulfurization using different passivated carbon nanoparticles by PEG-200

Cited by 25 publications

References 35 publications

Microwave-Assisted Adsorptive Desulfurization of Model Diesel Fuel Using Synthesized Microporous Rare Earth Metal-Doped Zeolite Y

Microwave-Assisted Adsorptive Desulfurization of Model Diesel Fuel Using Synthesized Microporous Rare Earth Metal-Doped Zeolite Y

Experimental and Computational Study of Organic Sulfur Removal Proficiency of (Ni, Cu, Co)‐Doped ZIF‐8 Adsorbents

Green Carboxylic Acid-Based Deep Eutectic Solvents as Solvents for Extractive Desulfurization

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