Adsorptive removal of nitrogen compounds from fuel oil by a poly ionic liquid PVIm-PXDC

New surface coordination photocatalytic systems that are inspired by natural photosynthesis have significant potential to boost fuel denitrification. Despite this, the direct synthesis of efficient surface coordination photocatalysts remains a major challenge. Herein, it is verified that a coordination photocatalyst can be constructed by coupling Pd and CTAB-modified ZnIn2S4 semiconductors. The optimized Pd/ZnIn2S4 showed a superior degradation rate of 81% for fuel denitrification within 240 min, which was 2.25 times higher than that of ZnIn2S4. From the in situ FTIR and XPS spectra of 1% Pd/ZnIn2S4 before and after pyridine adsorption, we find that pyridine can be selectively adsorbed and form Zn⋅⋅⋅C-N or In⋅⋅⋅C-N on the surface of Pd/ZnIn2S4. Meanwhile, the superior electrical conductivity of Pd can be combined with ZnIn2S4 to promote photocatalytic denitrification. This work also explains the surface/interface coordination effect of metal/nanosheets at the molecular level, playing an important role in photocatalytic fuel denitrification.

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Adsorptive removal of nitrogen compounds from fuel oil by a poly ionic liquid PVIm-PXDC

Cited by 2 publications

References 33 publications

Facile synthesis of magnetic ionic liquids/gold nanoparticles/porous silicon composite SERS substrate for ultra-sensitive detection of arsenic

Facile synthesis of magnetic ionic liquids/gold nanoparticles/porous silicon composite SERS substrate for ultra-sensitive detection of arsenic

Surface Coordination of Pd/ZnIn2S4 toward Enhanced Photocatalytic Activity for Pyridine Denitrification

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