“…[31,32] Since the year of 2009, Perovskite solar cells (PSCs) have attracted a great deal of attention from both the scientific and technological community due to their ever-growing PCE, lowcost raw materials, thin-film structures and facile fabrication processes. [20,[33][34][35][36][37][38][39][40][41][42][43] The PCE of single-junction PSCs has grown from the initial 3.8% in the year of 2009 to the latest more than 26%, approaching the theoretical limit efficiency of singlejunction PSCs, [35,43,44] and rivaling other existed PV semiconductors, such as multi(mono)-crystalline Si, [29,30] dye-sensitized, [45,46] gallium arsenide (GaAs), [47,48] copper indium gallium selenide (CIGS), [49,50] as well as quantum dot (QD) SCs. [51,52] However, PSCs still suffer from questionable stability under long-term operation condition, [34,36,41,53,54] rendering PSC commercialization.…”