Advances and Outlook of Boron–Hydrogen Containing Materials for Potential Clean Energy Applications: A Review

Li, Haojie; Yang, Bin; Wang, Xuetao; Yao, Zhen; Zhu, Yilin

doi:10.1021/acs.energyfuels.3c01393

Cited by 10 publications

(6 citation statements)

References 130 publications

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“…Through hydrolysis reactions, it can release high-purity green fuel hydrogen for energy production. Additionally, the generated borate salts are environmentally safe byproducts that can be recycled. , Compared to high-pressure hydrogen gas, the safety issues associated with the handling and transportation of NaBH 4 are easier to address …”

Section: Solid-state Hydrogen Storagementioning

confidence: 99%

Review of Hydrogen Storage Technologies and the Crucial Role of Environmentally Friendly Carriers

Fang,

Ding,

Chen

et al. 2024

Energy Fuels

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As the consumption rate of traditional fossil fuels continues to accelerate and environmental issues become increasingly severe, energy demand has become an urgent concern. In this context, hydrogen, as a clean and efficient energy source, has received widespread attention. However, because of its low density and gaseous nature, the storage of hydrogen faces challenging issues. Currently, storing hydrogen through compression and liquefaction methods is the most mature and widely adopted approach. However, the high pressure of gaseous storage and the issue of evaporation loss in liquid storage have driven the continuous development of solid-state storage. Among them, solid-state hydrogen storage methods, such as ammonia and metal hydrides, have received widespread attention. This is because these two storage methods do not involve carbon, which is more conducive to addressing environmental pollution issues. In this work, we review the gaseous, liquid, and solid-state storage methods of hydrogen; recapitulate hydrogen storage strategies; and investigate the latest developments in this field. Furthermore, we analyze the storage of carbonfree mediums, such as ammonia and certain metal alloy hydrides. These studies are expected to promote the healthy development of the hydrogen energy industry and make significant contributions to sustainable development.

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Section: Solid-state Hydrogen Storagementioning

confidence: 99%

Review of Hydrogen Storage Technologies and the Crucial Role of Environmentally Friendly Carriers

Fang,

Ding,

Chen

et al. 2024

Energy Fuels

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“…The applications of various metal hydrides as solid state hydrogen storage materials were extensively reviewed by Rusman and Dahari . Recently, Li et al, however, focused their investigation only on the use of boron hydrides in the storage of hydrogen, along with their ability to generate hydrogen, to act as reducing agents, and to be used for rocket fuel and fuel cells . In 2013 the Dalebrook team and Durbin et al and in 2015 Niaz et al and Zhang et al .…”

Section: Introductionmentioning

confidence: 99%

“…To the best of our knowledge, barring a few, most of the earlier review articles on hydrogen storage exclusively covered the topics of metal hydrides, ,, carbon materials, − 2D MXene-based materials, or MOFs. , Furthermore, the hydrogen storage abilities of MXene based materials are not covered in the review articles involving discussions on various hydrogen storage methods and materials. Hence, the main objective of the present Review is to convey the excitement surrounding the most recent status of various hydrogen storage materials and techniques, including MXene-based materials, and to give a thorough summary of our current scientific understanding.…”

Section: Introductionmentioning

confidence: 99%

Potential Benefits, Challenges and Perspectives of Various Methods and Materials Used for Hydrogen Storage

Panigrahi,

Chandu,

Motapothula

et al. 2024

Energy Fuels

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Fossil fuels, which are extremely harmful to the environment and not renewable, predominantly serve the majority of the world's energy needs. Currently, hydrogen is regarded as the fuel of the future due to its many advantages, such as its high calorific values, high gravimetric energy density, eco-friendliness, and nonpolluting nature, as well as being a zero-emission energy source. For sustainable global growth, it is essential to produce and store hydrogen on a large scale by utilizing renewable energy sources. However, hydrogen storage systems, particularly for vehicle on-board applications, face challenges in terms of developing energy-efficient and affordable techniques and materials due to hydrogen's buoyancy, lightness, and high diffusivity. This Review systematically discusses various hydrogen storage methods and materials, including physical storage like compressed gas, physical adsorption storage like carbon-based materials, metal−organic frameworks (MOFs), and other porous materials, as well as chemical storage like ammonia, methanol, formic acid, liquid organic hydrogen carriers (LOHCs), metal hydrides, and two-dimensional MXene-based materials. The advantages of various storage mechanisms are thoroughly discussed, as well as any potential implementation difficulties for realworld uses and future prospects.

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“…AB is a solid substance (white powder) at ambient conditions and is characterized by high hydrogen density (19.6 wt% H2), low molecular weight (30.7 g/mol), storage safety, high solubility in water, and long-term stability in an aqueous solution [35], [36], [37], [38], [39].…”

Section: Introductionmentioning

confidence: 99%

Hydrogen Generation via Catalytic Ammonia Borane Hydrolysis: A Patent Overview

Matsuda

2024

Preprint

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Hydrogen is one of the clean energies that will play an important role in energy selection for the coming low-carbon society. Ammonia borane (NH3BH3, abbreviated hereafter as AB) is considered as a promising hydrogen storage material due to its high hydrogen content (19.6 wt%), stability under ambient conditions (white powder), and favorable properties in dehydrogenation. AB can release hydrogen via pyrolysis, alcoholysis, hydrolysis, etc. Among these, AB hydrolysis is a safe and effective route, as it proceeds under mild conditions in the presence of an appropriate catalyst without the need for additional heat sources. For practical application, it is important to develop an efficient catalyst that further improves the hydrolytic dehydrogenation properties of AB. Many papers and reviews have been published, suggesting the research is at an advanced stage. On the other hand, since new technologies are often patented before they are put into practical use, the status of patent publication is of significant interest. This mini-review analyzes patent applications published up to 2023 on hydrogen generation via catalytic AB hydrolysis. The patent search yielded 99 patent publications, which were examined not only by country and research institution but also by two representative types of catalysts derived from noble metal (abbreviated hereafter as NM) and non-NM. Based on the analysis, future research and development was discussed.

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Advances and Outlook of Boron–Hydrogen Containing Materials for Potential Clean Energy Applications: A Review

Cited by 10 publications

References 130 publications

Review of Hydrogen Storage Technologies and the Crucial Role of Environmentally Friendly Carriers

Review of Hydrogen Storage Technologies and the Crucial Role of Environmentally Friendly Carriers

Potential Benefits, Challenges and Perspectives of Various Methods and Materials Used for Hydrogen Storage

Hydrogen Generation via Catalytic Ammonia Borane Hydrolysis: A Patent Overview

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