An artificial neural network (ANN) model has been developed for tensammetric determination of a series of Brijes (Brij 30, Brij 35, Brij 56, Brij 96) as nonionic surfactants. The tensammetric method is based on the measurement of the capacitive current of the mercury electrode after adsorption of surfactants. All Brijes were analyzed in the concentration range of 1.0 -100.0 mg mL
À1. The proposed method shows good sensitivity and applicability to the simultaneous determination of mixtures of four Brijes in aqueous solutions.