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In the oil pipeline transportation system, wax deposition will reduce the effective circulation area, weaken the overall pipeline transportation capacity, and even block the pipeline, which seriously threatens the safety of the pipeline flows. In the actual production of oil fields and the transportation of oil products, except for the single-phase waxy crude oil, under most conditions, operations are performed using multiphase mixed transportation, so it is necessary to determine the wax deposition characteristics in those pipeline systems. In this Review, three new wax deposition mechanisms proposed in recent years and several typical experimental devices were summarized, the wax deposition in oil–water and oil–gas flow systems and the wax–hydrate coupling deposition in oil–gas–water flow system flows were concluded; the mathematical models were also categorized based on the three flow systems. Meanwhile, it highlighted the fact that, in the two-phase flow, because of the complexity of the flow pattern and the presence of the second interface on the wax deposition process, independent theoretical research on the mechanism of wax deposition is particularly necessary; based on this, a more-accurate wax deposition prediction model can also be developed. For the coupled deposition of wax-hydrate in the three-phase flow system, experimental instruments such as FBRM, PVM and molecular dynamics simulations could be used to study the distribution characteristics and interaction rules of wax crystals and hydrate particles from a microscopic perspective. On the other hand, the mechanism of wax crystal and hydrate coupling deposition by additives such as antiwax agents, hydrate inhibitors, antipolymerization agents, and pipeline transportation conditions can be investigated experimentally to better control the deposition process during pipeline operation and ensure the safe flow in the transportation system.
In the oil pipeline transportation system, wax deposition will reduce the effective circulation area, weaken the overall pipeline transportation capacity, and even block the pipeline, which seriously threatens the safety of the pipeline flows. In the actual production of oil fields and the transportation of oil products, except for the single-phase waxy crude oil, under most conditions, operations are performed using multiphase mixed transportation, so it is necessary to determine the wax deposition characteristics in those pipeline systems. In this Review, three new wax deposition mechanisms proposed in recent years and several typical experimental devices were summarized, the wax deposition in oil–water and oil–gas flow systems and the wax–hydrate coupling deposition in oil–gas–water flow system flows were concluded; the mathematical models were also categorized based on the three flow systems. Meanwhile, it highlighted the fact that, in the two-phase flow, because of the complexity of the flow pattern and the presence of the second interface on the wax deposition process, independent theoretical research on the mechanism of wax deposition is particularly necessary; based on this, a more-accurate wax deposition prediction model can also be developed. For the coupled deposition of wax-hydrate in the three-phase flow system, experimental instruments such as FBRM, PVM and molecular dynamics simulations could be used to study the distribution characteristics and interaction rules of wax crystals and hydrate particles from a microscopic perspective. On the other hand, the mechanism of wax crystal and hydrate coupling deposition by additives such as antiwax agents, hydrate inhibitors, antipolymerization agents, and pipeline transportation conditions can be investigated experimentally to better control the deposition process during pipeline operation and ensure the safe flow in the transportation system.
Hydrate and wax deposition are the main challenges faced by the safe operation of a deepwater subsea pipeline due to low temperature, large elevation difference, and complex multiphase flow conditions. Chemical agents are important ways for treating hydrate and wax deposits. Oil, gas, and water produced by Liuhua 16-2 Oilfield are selected as experimental media to test and evaluate independently developed pour point depressants, wax deposition plugging removal agents, and low dose hydrate kinetic inhibitors. The static effect test results for three pour point depressants AN-12B, OF-1, and JN106-12B show that JN106-12B has the best performance, which can reduce the pour point of crude oil produced by Liuhua 16-2 Oilfield from 8°C to -19°C. When there is a risk of mixed deposition and blockage of hydrates and waxes during the fluid flow in the loop, simply adding pour point depressants or hydrate kinetic inhibitors cannot reduce the critical temperature at which the loop blockage occurs, and adding only wax deposition and blockage removal agents after the loop blockage cannot achieve blockage removal. However, if thermodynamic hydrate inhibitors such as methanol are added in advance, after the pipeline is blocked by wax deposition, the pipeline can be unblocked by adding the wax deposition unblocking agent JD150-B27. 20000ppm wax deposition plugging remover JD150-B27 takes about 40 minutes to achieve loop plugging removal. The evaluation results of different agents provide an important reference for the prevention and control of hydrate and wax deposition in the subsea pipeline of Liuhua 16-2 Oilfield.
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