Advances in disilylation reactions to access cis/trans-1,2-disilylated and gem-disilylated alkenes

Geng, Shasha; Pu, Yu; Wang, Siyu; Ji, Yanru; Feng, Zhang

doi:10.1039/d4cc00288a

Chem. Commun.

2024

DOI: 10.1039/d4cc00288a

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Advances in disilylation reactions to access cis/trans-1,2-disilylated and gem-disilylated alkenes

Shasha Geng,

Yu Pu,

Siyu Wang

et al.

Abstract: Organosilane compounds are widely used in both organic synthesis and materials science.

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trans‐Selective Element–Element′ Addition to Alkynes

Zhao,

Sun,

et al. 2024

ChemCatChem

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The trans‐addition of intermetallic σ‐bonds (E–E'; E E' = Si, B, Se, P, Sn, etc.) across alkynes has emerged as an exceptionally atom‐economical means of constructing multi‐substituted alkenes, which readily transform into densely functionalized and biologically active compounds. Compared to the widely studied cis‐E–E' additions, trans‐E–E' additions remain a more challenging and underdeveloped area. In this article, recent advances in trans‐E–E' additions are summarized, encompassing various interelement compounds such as Si–Si, B–B, Si–B, P–B, Se–B, and B–Sn. We aim to provide a deeper understanding of trans‐E–E' additions and facilitate the further development of synthetic methodologies and applications of vicinally trans‐bismetallated alkenes.

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trans‐Selective Element–Element′ Addition to Alkynes

Zhao,

Sun,

et al. 2024

ChemCatChem

View full text Add to dashboard Cite

show abstract

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Advances in disilylation reactions to access cis/trans-1,2-disilylated and gem-disilylated alkenes

Abstract: Organosilane compounds are widely used in both organic synthesis and materials science.

Cited by 1 publication

References 184 publications

trans‐Selective Element–Element′ Addition to Alkynes

trans‐Selective Element–Element′ Addition to Alkynes

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