We present an evaluation of laser potentialities of Yb 3+ -doped solid-state laser cubic crystals from concentration dependences of the 2 F 5/2 experimental decay time. We shall analyze few oxide and fluoride crystals of 4N (99.99) purity for commercialization. Experimental results will be related for two crystals: Yb 3+ -doped YAG garnet and Yb 3+ -doped KY 3 F 10 fluoride.Results can be extended today to laser ceramics of the same composition.