Advances in reactive polymeric surfactants for interface modification

Voronov, Stanislav; Kohut, Ananiy; Tarnavchyk, Ihor; Voronov, Аndriy

doi:10.1016/j.cocis.2014.03.010

Cited by 25 publications

(16 citation statements)

References 89 publications

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“…In an aqueous medium, they form micellar structures, which are able to solubilize hydrophobic substances [28]. This allows for the application of PM-1-MAc and PM-2-MAc as polymeric surfactants in emulsion polymerization.…”

Section: Methodsmentioning

confidence: 99%

“…The solubilization of the styrene monomer in emulsion polymerization followed by the formation of adsorption layers at the surface of latex particles occurs due to hydrophobic interactions and the hydration of ionized carboxylate groups oriented towards an aqueous phase ( Figure 3). The stability of the latex particles is achieved due to the combination of steric and electrostatic stabilization [28].…”

Section: Methodsmentioning

confidence: 99%

“…During thermolysis, the peroxide groups decompose to form tert-butoxy and macroradicals, which are able to initiate radical reactions of styrene polymerization [28,34]. The combination of the PM-1-MAc and PM-2-MAc macroradicals with the growing polystyrene chains leads to the attachment of the PM-1-MAc and PM-2-MAc macromolecules to the surface of latex Scheme 4.…”

Section: Methodsmentioning

confidence: 99%

“…During thermolysis, the peroxide groups decompose to form tert-butoxy and macroradicals, which are able to initiate radical reactions of styrene polymerization [28,34].…”

Section: Methodsmentioning

confidence: 99%

“…Amphiphilic copolymers poly(2-tert-butylperoxy-2-methyl-5-hexen-3-ine-co-maleic anhydride) (PM-1-MA) or poly[N-(tert-butylperoxymethyl)acrylamide]-co-maleic anhydride (PM-2-MA) were synthesized as described elsewhere [28][29][30]. All monomers were purified by vacuum distillation.…”

Section: Methodsmentioning

confidence: 99%

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Synthesis of Covalently Cross-Linked Colloidosomes from Peroxidized Pickering Emulsions

Popadyuk

Tarnavchyk

et al. 2016

Coatings

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Abstract:A new approach to the formation of cross-linked colloidosomes was developed on the basis of Pickering emulsions that were stabilized exclusively by peroxidized colloidal particles. Free radical polymerization and a soft template technique were used to convert droplets of a Pickering emulsion into colloidosomes.The peroxidized latex particles were synthesized in the emulsion polymerization process using amphiphilic polyperoxide copolymers poly(2-tert-butylperoxy-2-methyl-5-hexen-3-ine-co-maleic acid) (PM-1-MAc) or poly[N-(tert-butylperoxymethyl)acrylamide]-co-maleic acid (PM-2-MAc), which were applied as both initiators and surfactants (inisurfs). The polymerization in the presence of the inisurfs results in latexes with a controllable amount of peroxide and carboxyl groups at the particle surface. Peroxidized polystyrene latex particles with a covalently grafted layer of inisurf PM-1-MAc or PM-2-MAc were used as Pickering stabilizers to form Pickering emulsions. A mixture of styrene and/or butyl acrylate with divinylbenzene and hexadecane was applied as a template for the synthesis of colloidosomes. Peroxidized latex particles located at the interface are involved in the radical reactions of colloidosomes formation. As a result, covalently cross-linked colloidosomes were obtained. It was demonstrated that the structure of the synthesized (using peroxidized latex particles) colloidosomes depends on the amount of functional groups and pH during the synthesis. Therefore, the size and morphology of colloidosomes can be controlled by latex particle surface properties.

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Section: Methodsmentioning

confidence: 99%

Section: Methodsmentioning

confidence: 99%

Section: Methodsmentioning

confidence: 99%

“…During thermolysis, the peroxide groups decompose to form tert-butoxy and macroradicals, which are able to initiate radical reactions of styrene polymerization [28,34].…”

Section: Methodsmentioning

confidence: 99%

Section: Methodsmentioning

confidence: 99%

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Synthesis of Covalently Cross-Linked Colloidosomes from Peroxidized Pickering Emulsions

Popadyuk

Tarnavchyk

et al. 2016

Coatings

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Tailored Chemical Surface Modifications of Different Types of Thermoplastic Materials for Microfluidic Applications

Nagel

Weißpflog

Kroschwald

et al. 2015

Macro Materials & Eng

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The high temperature of the melt during thermoplastic processing is utilized for the surface modification of thermoplastic parts. The approach is demonstrated for polycarbonate as a reactive polymer and polystyrene as a non-reactive polymer. In case of polycarbonate, a polyamine is coupled to the polymer surface by chemical reaction. Functionalized latex beads are used for polystyrene, which are attached to the polymer surface by interdiffusion. Both surfaces adsorb selectively anionic or cationic dyes, respectively. The dyes are used as model compounds to demonstrate the potential of the surface modification approach for the fabrication of microfluidic parts. Those parts may be used for purification, accumulation, and reaction processes.

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Nano‐dispersion of fluorinated phosphonate‐modified nanodiamond in crystalline fluoropolymer matrix to achieve a transparent polymer/nanofiller hybrid

et al. 2018

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Well-dispersed polymer/organo-modified nanodiamond composites were created using crystalline fluorinated polymers as a matrix. All crystalline fluorinated polymers in this study were heat-resistant and became transparent via high-temperature drawing. The polyvinylidene-fluoride-based copolymer had a lowmelting point for a fluororesin and was easy to handle. Both fluorocarbonand hydrocarbon-modified nanodiamond formed well-dispersed nanocomposites in polyvinylidene-fluoride-based fluorocopolymers. The former was prepared due to excellent miscibility, and the latter was obtained by the so-called "nucleation effect". In this case, the nucleation effect was induced by the "epitaxial growth" resulting from the affinity between the end of the polymer chain and the modified chain and the similarity between the crystal structures of the modified-chain molecule and the corresponding polymer. However, fabricating a nanocomposite by combining hydrocarbon-modified fine particles and a fluorinated polymer is not universally feasible, and this system was unique. Ethylene-tetrafluoroethylene and perfluoroalkoxyalkane polymers showing high-melting points cannot form a nanohybrid with hydrocarbonmodified inorganic nanoparticles. In addition, to form a nanocomposite via melt-compounding, the desorption temperature of the modified chain of the outermost surface of the organo-nanodiamond had to be increased. Phosphonic acid containing fluorocarbon chainmodified nanodiamond satisfied all these requirements. The obtained nanocomposite exhibited enhanced physical properties and unique nanodiamond characteristics. POLYM. COMPOS., 40:E842-E855, 2019. POLYMER COMPOSITES-2019 FIG. 1. (a) Diagrams of application development by nanohybridization of several organo-modified NDs and polymers. (b) Schematic illustration of the research strategy in this study.

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Advances in reactive polymeric surfactants for interface modification

Cited by 25 publications

References 89 publications

Synthesis of Covalently Cross-Linked Colloidosomes from Peroxidized Pickering Emulsions

Synthesis of Covalently Cross-Linked Colloidosomes from Peroxidized Pickering Emulsions

Tailored Chemical Surface Modifications of Different Types of Thermoplastic Materials for Microfluidic Applications

Nano‐dispersion of fluorinated phosphonate‐modified nanodiamond in crystalline fluoropolymer matrix to achieve a transparent polymer/nanofiller hybrid

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