Advances in the chemistry of redox-active bis(imino)acenaphthenes (BIAN): A case of transition metal complexes

Fomenko, Iakov S.; Romashev, Nikolay F.; Gushchin, Artem L.

doi:10.1016/j.ccr.2024.215845

Coordination Chemistry Reviews

2024

DOI: 10.1016/j.ccr.2024.215845

|View full text |Cite

Advances in the chemistry of redox-active bis(imino)acenaphthenes (BIAN): A case of transition metal complexes

Iakov S. Fomenko,

Nikolay F. Romashev,

Artem L. Gushchin

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

2025

Publication Types

Select...

Article5

Relationship

Self Cite0

Independent5

Authors

Journals

Cited by 6 publications

References 356 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Novel organocatalytic system of R-bian, R-mian and NHPI for selective oxidation of cumene

Koshcheeva,

Kuznetsova,

Babushkin

et al. 2025

Molecular Catalysis

View full text Add to dashboard Cite

Novel organocatalytic system of R-bian, R-mian and NHPI for selective oxidation of cumene

Koshcheeva,

Kuznetsova,

Babushkin

et al. 2025

Molecular Catalysis

View full text Add to dashboard Cite

Copper-functionalized hydrochar from swine manure with complexation sites for selective adsorption of tetracycline antibiotics

Zhang,

Liu,

Yao

et al. 2025

Separation and Purification Technology

View full text Add to dashboard Cite

N-Heterocyclic Carbene-Derived Carbon Disulfide Radical Ligands for Palladium Diradicals

Park,

Hwang,

Shin

et al. 2024

J. Am. Chem. Soc.

View full text Add to dashboard Cite

N-heterocyclic carbenes (NHCs) are recognized for their ability to stabilize various main group radicals; however, NHC-derived, sulfur-based radicals remain rare. In this study, we successfully synthesized and characterized a series of palladium diradical complexes that featured new sulfur-based radical ligands from NHC–carbon disulfide adducts. Spectroscopic and computational characterizations of the palladium complexes confirmed the open-shell singlet ground state, which resulted from the antiferromagnetic coupling of two unpaired electrons on each ligand. Proton nuclear magnetic resonance relaxometry was used to experimentally confirm the presence of these unpaired electrons. Moreover, the redox behavior of the complexes was localized on the ligand center, confirming the redox activity of the ligands. The discovery of this sulfur-based, redox-active radical ligand underscores the versatility and significance of NHC-derived radicals, thereby expanding the repertoire of radical ligands and opening new avenues for advanced material and catalytic systems.

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Advances in the chemistry of redox-active bis(imino)acenaphthenes (BIAN): A case of transition metal complexes

Cited by 6 publications

References 356 publications

Novel organocatalytic system of R-bian, R-mian and NHPI for selective oxidation of cumene

Novel organocatalytic system of R-bian, R-mian and NHPI for selective oxidation of cumene

Copper-functionalized hydrochar from swine manure with complexation sites for selective adsorption of tetracycline antibiotics

N-Heterocyclic Carbene-Derived Carbon Disulfide Radical Ligands for Palladium Diradicals

Contact Info

Product

Resources

About