2021
DOI: 10.6023/a21050224
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Advances on Atmospheric Oxidation Mechanism of Typical Aromatic Hydrocarbons

Abstract: Aromatic hydrocarbons are important precursors of ozone and secondary organic aerosols in the urban atmosphere, which have important impact on air pollution, climate change and human health. Thus the research on the oxidation mechanism of aromatic hydrocarbons has become one of the most challenging hotspots topics in atmospheric environmental chemistry. This paper reviews the recent studies of aromatic hydrocarbons oxidation mechanism, discusses the reaction channels and influencing factors during the oxidatio… Show more

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Cited by 8 publications
(6 citation statements)
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“…By combining the information from ESP, ALIE, and Fukui function f 0 ( r ), it is clear that the benzene ring on BHT and the tert -butyl group near the phenolic hydroxyl side are more likely to react with OH radicals. It is worth noting that it is consistent with related reports. ,, Although a large number of research studies show that BHT can form a variety of metabolites with the OH radical. However, the mechanism of BHT degradation in the environment to produce isobutene is unclear.…”
Section: Resultssupporting
confidence: 91%
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“…By combining the information from ESP, ALIE, and Fukui function f 0 ( r ), it is clear that the benzene ring on BHT and the tert -butyl group near the phenolic hydroxyl side are more likely to react with OH radicals. It is worth noting that it is consistent with related reports. ,, Although a large number of research studies show that BHT can form a variety of metabolites with the OH radical. However, the mechanism of BHT degradation in the environment to produce isobutene is unclear.…”
Section: Resultssupporting
confidence: 91%
“…The oxidation of BHT can take place on the aromatic ring, and in the p -methyl, t -butyl groups . The hydroxyl radicals in the environment are very importantly related to the degradation of benzene compounds, , and the alkyl substituents on the benzene ring provide many active sites for hydrogen abstraction of OH radicals …”
Section: Resultsmentioning
confidence: 99%
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