Advances on Manufacturing of POSS Reinforced Resin Matrix Composites

Wang, Dan-Yong; Liu, Juncong; Chen, Yiwei; Li, Shu-Hu; Wei, Huazhen; Xia, Min

doi:10.2991/icmsa-15.2015.66

Proceedings of the 2015 International Conference on Material Science and Applications 2014

DOI: 10.2991/icmsa-15.2015.66

|View full text |Cite

Advances on Manufacturing of POSS Reinforced Resin Matrix Composites

Dan-Yong Wang¹,

Juncong Liu²,

Yiwei Chen³

et al.

Abstract: Abstract. POSS with cage-like hybrid molecules composed of silicon and oxygen has raised great interests of materials researchers owing to its excellent mechanical and thermal properties, such as tensile strength, tensile modulus and glass transition temperature Tg. And it has been widely used in electronics, automotives and multiple applications. The four basic manufacturing advances on POSS reinforced resin matrix composites were revealed in this paper and the corresponding conclusions were given. The advanc… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2018

2024

Publication Types

Select...

Article2

Relationship

Self Cite0

Independent2

Authors

Journals

Cited by 2 publications

References 42 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Catalytic effect of N-phenylaminopropyl polyheadral oligomeric silsesquioxane in the synthesis of hybrid nanocomposites based on polycyanurate

Grigoryeva,

Shulzhenko,

Gusakova

et al. 2024

Polim. z.

View full text Add to dashboard Cite

Organic-inorganic nanocomposites based on heat-resistant crosslinked polycyanurate (PCN) and N-phenylaminopropyl polyhedral oligomeric silsesquioxane (NPAP-POSS), containing eight reactive secondary amino groups, were synthesized using the in situ reactive formation method. Fourier transmission infrared (FTIR) spectroscopy and dynamic differential scanning calorimetry (DSC) methods were used to study the effect of NPAP-POSS on the kinetics of bisphenol E dicyanate ester (DCBE) polycyclotrimerization during the formation of PCN in PCN/NPAP-POSS nanocomposites. The content of the nanofiller was varied from 0.05 to 1.00 wt.%. Based on the results of FTIR spectral studies, the main kinetic peculiarities of PCN formation were found and their changes under the action of NPAP-POSS nanofiller were determined. A significant catalytic effect of NPAP-POSS on the polycyclotrimerization of DCBE was found, which is confirmed by a decrease in the time of the onset of auto-acceleration, an acceleration of the conversion of cyanate groups of DCBE and the formation of triazine cycles of PCN, an increase in the values of the maximum reaction rate, a decrease in the duration of the reaction, etc. The dynamic DSC method also confirmed the catalytic effect of NPAP-POSS on the formation of PCN in the nanocomposites and established the main kinetic characteristics depending on the content of the nanofiller: a significant decrease in the temperature of the exothermic maximum, an increase in the reaction enthalpy, non-monotonic changes in the induction period and reaction rate, etc. From the analysis of the experimental data, it was concluded that the detected changes in the kinetics of the in situ reaction formation of PCN/NPAP-POSS nanocomposites and the recorded catalytic effect of the nanofiller are due to the fact that two chemical processes occur during the synthesis of the nanocomposites: chemical interaction of –O–C≡N groups of DCBE with secondary –NH groups of NPAP-POSS, which led to further embedding of nanoparticles into the resulting polymer matrix and the direct polycyclotrimerization of DCBE with formation of hybrid polycyanurate network. Schemes of the sequential reactions explaining the catalytic effect of the nanofiller in the synthesis of hybrid PCN/NPAP-POSS nanocomposites are proposed. It was concluded that under the selected conditions of the synthesis, the greatest catalytic effect of the nanofiller is manifested at its content of 0.10 wt.%, since for this sample the maximum shift of the reaction exothermic peak towards lower temperatures, the maximum reaction rate, and the minimum induction period and reaction start temperature were recorded. The results of the research make it possible to optimize the synthesis of heat-resistant materials promising for use in special-purpose structures.

show abstract

Catalytic effect of N-phenylaminopropyl polyheadral oligomeric silsesquioxane in the synthesis of hybrid nanocomposites based on polycyanurate

Grigoryeva,

Shulzhenko,

Gusakova

et al. 2024

Polim. z.

View full text Add to dashboard Cite

show abstract

The Adhesive Strength of Epoxy/Sol-Gel Materials Modified by Various Ratio of γ-Al2O3 Nanoparticles

Ali

May

Wang

et al. 2018

J. Coat. Sci. Technol.

View full text Add to dashboard Cite

In this study, the use of sol-gel/epoxy adhesive based on the combination of organic and inorganic components within the adhesive matrix have been studied. The combination of different amounts of ᵞ-Al2O3 nano-particles to the adhesive matrix was evaluated. Mild steel specimens were prepared for lap joints, which were cured in an oven at 200°C for 16 hours.The bond strength of the sol-gel/epoxy matrix was investigated using a universal tensile test machine. The presence of Al-OH and/or Si-OH bonds increases causing an increase in the strength of the bulk material. This process is seen through the appearance of an absorption peak shoulder which appears in the range of ~ 1088 to1100 cm -1 which corresponds to Al-O-Si or Si-O-Si. The maximum adhesive strength of composite sol-gel/epoxy adhesive recorded was 23±0.4 MPa. This was obtained when small amounts of γ-Al2O3 nanoparticles (4.0 wt%), were incorporated within the matrix. However, as the level of these inorganic materials in the adhesive matrix increased further, the adhesive shear strength gradually decreased. At a high ratio of γ-Al2O3 particles, poor interfacial bonding or adhesion between the filler and the adhesive matrix is recorded. Scanning Electron Microscopy (SEM) is used to investigate the fracture surface with 4.0 wt% γ-Al2O3, the scanning shows a very small distance of cracks, suggesting the material may act as a barrier to crack propagation and thus increases the energy required for fracture.

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Advances on Manufacturing of POSS Reinforced Resin Matrix Composites

Cited by 2 publications

References 42 publications

Catalytic effect of N-phenylaminopropyl polyheadral oligomeric silsesquioxane in the synthesis of hybrid nanocomposites based on polycyanurate

Catalytic effect of N-phenylaminopropyl polyheadral oligomeric silsesquioxane in the synthesis of hybrid nanocomposites based on polycyanurate

The Adhesive Strength of Epoxy/Sol-Gel Materials Modified by Various Ratio of γ-Al2O3 Nanoparticles

Contact Info

Product

Resources

About