Aerobic alcohol oxidation catalyzed by a new, oxygen-bridged heterometallic compound [PPh4][Ru(N)Me2(μ2-O)2Pd((−)-sparteine)]

Kuiper, Jesse; Shapley, Patricia A.

doi:10.1016/j.jorganchem.2006.12.014

Cited by 14 publications

(6 citation statements)

References 23 publications

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“…The addition of molecular sieves to trap the water during the reactions greatly improved the yields. 240 The cluster [Ru 4 Pt 2 (CO) 18 ] was used to prepared carbonsupported RuPt/C NPs for the electrocatalytic oxidation of methanol (to CO 2 most likely). It was more active than commercial catalysts, probably due to the high dispersion of very small NPs.…”

Section: Scheme 16mentioning

confidence: 99%

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Multimetallic Catalysis Based on Heterometallic Complexes and Clusters

2014

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Section: Scheme 16mentioning

confidence: 99%

“…In particular, in the presence of O 2 , it catalyzed the conversion of allyl alcohol to propionaldehyde and acrolein in a 1:2 ratio, and the oxidation of benzyl alcohol to benzaldehyde. The addition of molecular sieves to trap the water during the reactions greatly improved the yields …”

Section: Reactions In the Presence Of Heterometallic Catalystsmentioning

confidence: 99%

Multimetallic Catalysis Based on Heterometallic Complexes and Clusters

2014

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“…However, it is noted that there are examples of heterometallic Ru VI -nitrido complexes behaving as catalysts for oxidation of alcohols (Scheme 3). [78][79][80][81] The chromate ion or thio derivatives of the types M(dppe)(S) 2 as mono-/bidentate metalloligand coordinate to nitrido(dialkyl)ruthenium(VI) species. For example, the heterobimetallic to coordinate with ruthenium.…”

Section: Ru VI -Nitrido Complexesmentioning

confidence: 99%

“…The rutheniumpalladium analogues 3 with m-oxo ligand are generated from reaction of [PPh 4 ][Ru(N)(OH) 2 Me 2 ] and Pd(OSiMe 3 ) 2 ((2)-sparteine). 81 Multidentate ligands usually are strong s donors capable of encapsulating metal ions in high oxidation states. The geometric constraints of these multidentate ligands will frequently influence the overall geometry and the properties of the complex.…”

Section: Ru VI -Nitrido Complexesmentioning

confidence: 99%

Recent developments in ruthenium nitrido complexes

Liang

2013

RSC Adv.

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Metal nitrido complexes are frequently invoked as key intermediates in numerous synthetic, catalytic and enzymatic transformations, such as C-N and H-N bond-formation, nitrogen atom/group transfer reactions and biological nitrogen fixation by nitrogenase enzyme. Ruthenium nitrido complex is one of the most important metal nitrido complexes. There is a growing interest in chemistry of Ru-nitride. Over the past decade, numerous chemically activated ruthenium nitrido complexes have been discovered. This short review summarizes recent advances in the synthesis and reactivity of these complexes.

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“…The main areas of application are the polymerization of various alkenes [8 -10] and the catalytic enhancement of organic reactions [11 -13]. Furthermore, oxidation reactions can be facilitated by the use of heterobimetallic catalysts [14,15]. To combine two metals in one molecule it is often feasible to use Janus-Head ligands [16 -20].…”

Section: Introductionmentioning

confidence: 99%