Aerobic bimetallic catalysis for oxy-alkynylation of allenes

Fan, Junjie; Zhang, Dongjie; Shi, Yaqi; Fu, Chunling; Ma, Shengming

doi:10.1039/d4qo00622d

Org. Chem. Front.

2024

DOI: 10.1039/d4qo00622d

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Aerobic bimetallic catalysis for oxy-alkynylation of allenes

Junjie Fan,

Dongjie Zhang,

Yaqi Shi

et al.

Abstract: Here we report a conceptual protocol to construct 4-alkynyl furan-2(5H)-one derivatives efficiently through Rh(III)/Cu(I) co-catalyzed highly regioselective oxy-alkynylation of 2,3-allenoic acids with terminal alkynes under mild aerobic conditions with atom...

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Visible light-mediated gold-catalyzed alkynylative cyclization of allenoates with iodoalkynes for the synthesis of β-alkynyl-γ-butenolides

He,

Zhong,

Marion

et al. 2024

Org. Chem. Front.

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Visible light-mediated gold-catalyzed alkynylative cyclization of allenoates with iodoalkynes for the synthesis of β-alkynyl-γ-butenolides

He,

Zhong,

Marion

et al. 2024

Org. Chem. Front.

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show abstract

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Aerobic bimetallic catalysis for oxy-alkynylation of allenes

Abstract: Here we report a conceptual protocol to construct 4-alkynyl furan-2(5H)-one derivatives efficiently through Rh(III)/Cu(I) co-catalyzed highly regioselective oxy-alkynylation of 2,3-allenoic acids with terminal alkynes under mild aerobic conditions with atom...

Cited by 1 publication

References 59 publications

Visible light-mediated gold-catalyzed alkynylative cyclization of allenoates with iodoalkynes for the synthesis of β-alkynyl-γ-butenolides

Visible light-mediated gold-catalyzed alkynylative cyclization of allenoates with iodoalkynes for the synthesis of β-alkynyl-γ-butenolides

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