The lack of freshwater
has been threatening many people who are
living in Africa, the Middle East, and Oceania, while the discovery
of freshwater harvesting technology is considered a promising solution.
Recent advances in structured surface materials, metal–organic
frameworks, hygroscopic inorganic compounds (and derivative materials),
and functional hydrogels have demonstrated their potential as platform
technologies for atmospheric water (i.e., supersaturated fog and unsaturated
water) harvesting due to their cheap price, zero second energy requirement,
high water capture capacity, and easy installation and operation compared
with traditional water harvesting methods, such as long-distance water
transportation, seawater desalination, and electrical dew collection
devices in rural areas or individual-scale emergent usage. In this
contribution, we highlight recent developments in functional materials
for “passive” atmospheric water harvesting application,
focusing on the structure–property relationship (SPR) to illustrate
the transport mechanism of water capture and release. We also discuss
technical challenges in the practical applications of the water harvesting
materials, including low adaptability in a harsh environment, low
capacity under low humidity, self-desorption, and insufficient solar-thermal
conversion. Finally, we provide insightful perspectives on the design
and fabrication of atmospheric water harvesting materials.