Aerogels are typically developed from gelatinous networks and utilized in applications focused on sorption, filtration, tissue scaffold, acoustic, and thermal insulations. [2,5,6] The first aerogel was produced via supercritical CO 2 drying of silica gel by Kistler in 1930s. [7] Subsequently, other types of inorganic aerogels were developed, including clay, metal oxides, graphene, and carbon aerogels for diverse applications, including but not limited to lithium-ion batteries, supercapacitors, sensors, and catalysis. [2,8] These inorganic aerogels lacked mechanical flexibility, leading to the discovery of their organic counterparts. Even though the first organic aerogel was produced from cellulose ninety years ago, [7] it was not until a few decades back that organic aerogels gained attention due to their flexibility, sustainable nature of the precursors, and tunable surface functionalities. [8] So far, a wide variety of organic aerogels have been produced from various precursors, including synthetic polymers and biopolymers. Cellulose, alginate, chitosan, pectin, and starch are the most important biopolymers used for the fabrication of biopolymer aerogels. [2] Research focusing on aerogels developed from cellulose has gained significant attention, resulting in an exponential rise in the number of published literature in the last decade (Figure 1). [9][10][11] Cellulose is the most abundant biopolymer (Figure 2a), which is extracted from readily available natural resources such as wood, cotton, hemp, and other plant-based materials. [12] Cellulose-based materials have been used in advanced applications for hundreds of years. [9,[13][14][15] Due to the hierarchical assembly of cellulose chains, different types of nanostructured cellulose (Figure 2d-f), including cellulose nanofibrils (CNF), cellulose nanocrystals (CNC), and bacterial cellulose (BC) are extracted from various resources. CNFs are the smallest structural unit that is extracted from natural cellulose fibers. Depending on the extraction method, and post-processing treatments, CNFs exhibit high aspect ratio with diameters ranging from 3-100 nm and lengths exceeding the micrometer range. [3,16] Finer fibrils can be extracted using pretreatment oxidation of CNF with 2,2,6,6-tetramethylpiperidine-1-oxyl radical (TEMPO) known as TEMPO-CNF (i.e., 4-10 nm diameter). [17] CNCs are crystalline rod-like (or rice-husk like) materials with typical diameter of 5-20 nm, length of 50-350 nm, and aspect ratio of The brittle nature of early aerogels developed from inorganic precursors fueled the discovery of their organic counterparts. Prominent among these organics are cellulose aerogels because of their natural abundance, biocompatibility, sustainable precursors, and tunable properties. The hierarchical structure of cellulose, from polymers to nano/microfibers, further facilitates fabrication of materials across multiple length scales with added applicability. However, the inherent flammability, structural fragility, and low thermal stability have limited their use...