The results presented are the first complete analysis of inorganic soluble ions in a tropical savannah region. Atmospheric particles were collected in six rural Venezuelan savannah sites. Concentrations and size distribution of NO3, SO ]-, CI-, PO43-, NH], Na +, K ÷, Ca 2÷ and Mg 2÷ were determined in samples collected with Hi Vol samplers equipped with five-stage cascade impactors. Concentrations were higher in the dry season, with a maximum during the burning periods. Using Na ÷ as a reference, the results show a deficit of CI-and, with the exception of Mg 2÷, an enrichment of all other ions with respect to marine aerosols. Significant variations were observed in particle-size distribution between different periods. Various pairs of ions present similar size distributions: SO 2-and NI-~4; Cl-and Na ÷; PO 3-and K ÷; Ca 2÷, Mg 2+ and NO 3 ; indicating that the ions were produced by the same source and/or were involved in similar atmospheric processes. Possible primary sources, the gas-to-particle atmospheric process, environmental implication of long-range transport of nutrients during dry seasons, etc., are discussed.