The effect of urbanization on the urban thermal environment (UTE) has attracted increasing research attention because its significant effects on local weather and climate, and serious consequences for people. However, systematic study of the relationship between urbanization and UTE has been undertaken only to a limited extent. Using quantitative thermal remote sensing and multi-buffer ring method and multiple spatial scales method, here we analyze Landsat TM/ETM+ images of Zhengzhou in Central China acquired on four different dates in 2017 to investigate the spatiotemporal variations, trends, and driving force in the land surface temperature (LST). Our results showed that LST generally increased with urbanization intensity. This trend was extremely obvious in spring and summer, weak in winter, and slightly downward in autumn. Moreover, PLAND (e.g., percentage of impervious surface in a landscape) has the most significant effect on urban LST, and generally increases as the spatial scale becomes larger. In conclusion, the study recommends that urban planning in Zhengzhou should prioritize PLAND, especially at large spatial scales. These results provide a scientific reference for urban planners who are committed to the sustainable development of Zhengzhou City.