2022
DOI: 10.1021/acs.inorgchem.2c03113
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Against the Norm: Non Irving–Williams Transmetalation in Transition Metal Dimers

Abstract: We report the synthesis and characterization of three dinuclear 3d3d′ complexes, CuCu ( [ C u 2 I I L ( N O 3 ) 2 ] ), MnMn ( [ M n 2 I I L ( M e O H ) 2 ( N O 3 ) 2 ] ), and CuMn ([CuIIMnII L(NO3)2]), that utilize the ligand, H2 L (6,6′-dimethoxy-2,2’-[(1,3-propylene)dioxybis(nitrilomethylidyne)]diphenol). The relative stabilities of these complexes were investigated using experimental and computational techniques, revealing a non-Irving-Williams transmeta… Show more

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Cited by 27 publications
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