An early-type, massive, short-period (P orb = 2 d .310951) eclipsing spectroscopic binary DN Cas has been re-visited with new spectral and photometric data. The masses and radii of the components have been obtained as M1 = 19.04 ± 0.07M⊙, M2 = 13.73 ± 0.05M⊙ and R1 = 7.22 ± 0.06R⊙, R2 = 5.79 ± 0.06R⊙, respectively. Both components present synchronous rotation (Vrot1 = 160 km s −1 , Vrot2 = 130 km s −1 ) with their orbit. Orbital period analysis yielded a physically bound additional component in the system with a minimum mass of M3 = 0.88M⊙ orbiting in an eccentric orbit (e = 0.37 ± 0.2) with an orbital period of P12 = 42 ± 9 yrs. High precision absolute parameters of the system allowed us to derive a distance to DN Cas as 1.7±0.2 kpc which locates the system within the borders of the Cas OB6 association (d = 1.8 kpc; Mel'nik & Dambis, 2009). The space velocities and the age of DN Cas are in agreement with those of Cas OB6. The age of DN Cas (τ =3-5 Myr) is found to be 1-2 Myr older than the embedded clusters (IC 1795, IC 1805 and IC 1848 in the Cas OB6 association, which implies a sequential star formation in the association.