2015
DOI: 10.1007/s12039-015-0899-6
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Aggregation and electrochemical properties of 1-(4-chlorophenyl)-3-dodecanoylthiourea: A novel thiourea-based non-ionic surfactant

Abstract: A novel thiourea-based non-ionic surfactant 1-(4-chlorophenyl)-3-dodecanoylthiourea (4CPDT) was synthesized from decanoyl chloride, potassium thiocyanate and 4-chloroanline in high yield. The structural chemistry of the compound was done by multiple nuclear NMR (1 H, 13 C) and FT-IR. UV-Visible spectrophotometry and pendant drop methods were used to evaluate their critical micelle concentration in ethanol and hexane. This surfactant showed very low solubility in water, and interestingly low but well-defined, s… Show more

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Cited by 2 publications
(1 citation statement)
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“…Low CMC designated them as promising cleaning agents [120]. The same research group documented non-ionic surfactants 27 and 28 containing a thiourea linker in two different reports [121,122]. Due to sub-millimolar CMCs in the organic solvents and very low water solubility, it was suggested that the surfactants are reasonably amphiphobic.…”
Section: As Surfactantsmentioning
confidence: 99%
“…Low CMC designated them as promising cleaning agents [120]. The same research group documented non-ionic surfactants 27 and 28 containing a thiourea linker in two different reports [121,122]. Due to sub-millimolar CMCs in the organic solvents and very low water solubility, it was suggested that the surfactants are reasonably amphiphobic.…”
Section: As Surfactantsmentioning
confidence: 99%