Aggregation of derivatives of benz[C, D]indole dyes: Effect of the side group and ambient temperatures

Abstract

Two pairs of benz[c,d]indole dyes with the same chromophore in each pair have been studied in respect to their ability to form thin films through thermal evaporation in vacuum. Electronic absorption spectra of the films revealed that despite very slight variations in molecular structure different aggregate structures can be formed in the films. It has been shown that substitution of one carbon atom in the dye structure by a sulfur atom leads to crucial sensitivity of the aggregate structure to film thickness and substrate temperature. On the other hand, dye with bulky side groups was less sensitive to the changes in the deposition conditions.

Tuned aggregation and film self-assembly of monomethincyanine dyes through variation of their monomer structure

“…One of the main factors that defines the intermolecular interaction is the chemical structure of molecule, which can be tuned to drive the structure of the condensed film overall and to change its physical properties, respectively. Monomethincyanine dyes belong to polymethine dyes serving as convenient model objects that allow one to understand how slight variation in the molecular structure can influence formation of the aggregate or bulk structure [4][5][6][7]. These dyes have relatively short length and are stable upon thermal evaporation in vacuum [8].…”