Aggregation of Octa-[(4’-benzo-15-crown-5)oxy]phthalocyanines in Polar Solvents

Novel complexes of cobalt(II) with sulfonated derivatives of phthalocyanines are synthesized. The influence of the sulfonated group's number in peripheral substituent on solubility of macrocycle and ability to form ordered structures in solution is showed. Transition from H-aggregates to monomeric phthalocyanine structures and sandwich-type dimers was found during formation of metallophthalocyanine complexes with 1,4-diazabicyclo[2.2.2]octane. The catalytic activity of metallophthalocyanines was studied on the model of Merox process.

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Aggregation of Octa-[(4’-benzo-15-crown-5)oxy]phthalocyanines in Polar Solvents

Cited by 3 publications

References 7 publications

Effect of the solvation properties of the solvent on the formation of associated structures of water-soluble Co(II) phthalocyanines

Effect of the solvation properties of the solvent on the formation of associated structures of water-soluble Co(II) phthalocyanines

The Processes of Crown-Substituted Magnesium Phthalocyaninate Dissolution in Water in the Presence of Alkyltrimethylammonium Bromides

A new water-soluble sulfonated cobalt(II) phthalocyanines: Synthesis, spectral, coordination and catalytic properties

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