2022
DOI: 10.1002/batt.202200155
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Aging Effect of Catechol Redox Polymer Nanoparticles for Hybrid Supercapacitors

Abstract: Redox-polymer nanoparticles are a promising solution to avoid the detrimental dissolution of organic electrode materials while showing discrete redox processes. In this work, catechol-based redox-active polymer nanoparticles (cRPNs) were synthesized through one-step emulsion polymerization with a tunable size from 25 to 150 nm. The fresh cRPNs were characterized and showed a reversible redox process centered at 0.50 V (vs. Ag/ AgCl) in 1 M H 2 SO 4 . Unexpectedly, the cRPN latex aged after days passing from wh… Show more

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Cited by 2 publications
(1 citation statement)
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“…Similar observations regarding the effects of synthesis details have been reported for a composite of such nanotubes coated with MnO 2 [ 79 ]. A very specific type of ageing was encountered with catechol-based polymeric redox materials [ 80 ]. A few days after reparation, a change of colour of the material already indicated an autoxidation of the catechol groups and subsequent crosslinking associated with a higher redox potential.…”
Section: Causes and Mechanismsmentioning
confidence: 99%
“…Similar observations regarding the effects of synthesis details have been reported for a composite of such nanotubes coated with MnO 2 [ 79 ]. A very specific type of ageing was encountered with catechol-based polymeric redox materials [ 80 ]. A few days after reparation, a change of colour of the material already indicated an autoxidation of the catechol groups and subsequent crosslinking associated with a higher redox potential.…”
Section: Causes and Mechanismsmentioning
confidence: 99%