2019
DOI: 10.1039/c9sm00366e
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Aging phenomena during phase separation in fluids: decay of autocorrelation for vapor–liquid transitions

Abstract: We performed molecular dynamics simulations to study relaxation phenomena during vapor-liquid transitions in a single component Lennard-Jones system. Results from two different overall densities are presented; one in the neighborhood of the vapor branch of the coexistence curve and the other being close to the critical density. The nonequilibrium morphologies, growth mechanisms and growth laws in the two cases are vastly different. In the low density case growth occurs via diffusive coalescence of droplets in … Show more

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Cited by 11 publications
(27 citation statements)
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“…The deviations from the exponential-like behavior, at n / n 0 = n d , after certain times, are primarily because of PD, that includes the effects of lockdown, and this fact is analogous to the appearance of the finite-size effects [15, 38]. In a standard phase transition problem, the characteristic length at the departure of a quantity from the thermodynamic limit behavior, i.e., the length at the onset of finite-size effects, is proportional to the system size [38, 42, 43]. Thus, instead of the actual size N / n 0 of the system, here one can work with n d , value of which is country specific.…”
Section: Resultsmentioning
confidence: 99%
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“…The deviations from the exponential-like behavior, at n / n 0 = n d , after certain times, are primarily because of PD, that includes the effects of lockdown, and this fact is analogous to the appearance of the finite-size effects [15, 38]. In a standard phase transition problem, the characteristic length at the departure of a quantity from the thermodynamic limit behavior, i.e., the length at the onset of finite-size effects, is proportional to the system size [38, 42, 43]. Thus, instead of the actual size N / n 0 of the system, here one can work with n d , value of which is country specific.…”
Section: Resultsmentioning
confidence: 99%
“…Similar analyses [37, 38, 42, 43] have been performed for quantifying the singularities in the nonequilibrium domain. The current problem is more closely related to this.…”
Section: Modelmentioning
confidence: 99%
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“…Furthermore, in an evolving system the time translation invariance is violated, implying different relaxation rates when probed by starting from different waiting times (t w ) or ages of the system. Such aging property [6][7][8][9][10][11][12][13][14][15][16][17][18][19][20] is often investigated via the two time order-parameter autocorrelation function [6] C ag (t, t w ) = ψ( r, t w )ψ( r, t) − ψ( r, t w ) ψ( r, t) , (5) with t > t w . Despite different decay rates for different t w , C ag (t, t w ) in many systems exhibits the scaling property [7] C ag (t, t w ) ∼ (ℓ/ℓ w ) −λ ,…”
Section: Introductionmentioning
confidence: 99%
“…Be it a colony of bacteria or a herd of sheep, clustering in active matter systems, containing self-propelling particles [1][2][3][4][5][6][7], is rather common. Phenomena associated with such assemblies received much attention in the passive scenario [8][9][10][11][12][13][14][15][16][17][18][19][20][21][22][23]. Currently, for experimentalists and theorists alike, the focus is on the active counterpart [1][2][3][4][5][6][7][24][25][26][27][28][29][30][31][32][33][34].…”
Section: Introductionmentioning
confidence: 99%