2021
DOI: 10.1002/zaac.202100098
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AgNO3⋅NH4NO3 – an enigmatic double‐salt type “decomposition intermediate” of diamminesilver(I) permanganate

Abstract: Dedicated to Prof. Wolfgang Kaim on the Occasion of his 70th BirthdayThe 1 : 1 type double salt of AgNO 3 and NH 4 NO 3 (NH 4 NO 3 • AgNO 3, compound 1) was prepared and its Raman spectrum was evaluated. IR and far-IR spectra of compound 1 and its deuterated analog (ND 4 NO 3 • AgNO 3 , compound 1-D) were also studied. We identified two types of nitrate ions, one had a relatively strong, whereas the other is only weakly hydrogen bonded to the surrounding ammonium ions. The thermal decomposition features of com… Show more

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Cited by 4 publications
(2 citation statements)
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“…Spectroscopical measurements (IR, far-IR, and Raman) were performed on Bruker Alpha FT-IR spectrometer (Bruker, Ettingen, Germany), a BioRad-Digilab FTS-60A spectrometer (Biorad, Austin, TX, USA), and a Horiba Jobin-Yvon LabRAM-type microspectrometer (Horiba Jobin Yvon Gmbh, Bensheim, Germany), respectively, and the details of measurements are given in our previous papers [20,28,30].…”
Section: Methodsmentioning
confidence: 99%
“…Spectroscopical measurements (IR, far-IR, and Raman) were performed on Bruker Alpha FT-IR spectrometer (Bruker, Ettingen, Germany), a BioRad-Digilab FTS-60A spectrometer (Biorad, Austin, TX, USA), and a Horiba Jobin-Yvon LabRAM-type microspectrometer (Horiba Jobin Yvon Gmbh, Bensheim, Germany), respectively, and the details of measurements are given in our previous papers [20,28,30].…”
Section: Methodsmentioning
confidence: 99%
“…The classical analytical and basic instrumental measurements were taken using methods and instruments described in detail in our earlier papers [1][2][3][4][5][6][7]. The most essential conditions of the measurement methods are listed below.…”
Section: Methodsmentioning
confidence: 99%