Purpose of Review
Fine particulate matter (PM
2.5
) and ground-level ozone (O
3
) pose a significant risk to human health. The World Health Organization (WHO) has recently revised healthy thresholds for both pollutants. The formation and evolution of PM
2.5
and O
3
are however governed by complex physical and multiphase chemical processes, and therefore, it is extremely challenging to mitigate both pollutants simultaneously. Here, we review mechanisms and discuss the science-informed pathways for effective and simultaneous mitigation of PM
2.5
and O
3
.
Recent Findings
Global warming has led to a general increase in biogenic emissions, which can enhance the formation of O
3
and secondary organic aerosols. Reductions in anthropogenic emissions during the COVID-19 lockdown reduced PM
2.5
; however, O
3
was enhanced in several polluted regions. This was attributed to more intense sunlight due to low aerosol loading and non-linear response of O
3
to NO
x
. Such contrasting physical and chemical interactions hinder the formulation of a clear roadmap for clean air over such regions.
Summary
Atmospheric chemistry including the role of biogenic emissions, aerosol-radiation interactions, boundary layer, and regional-scale transport are the key aspects that need to be carefully considered in the formulation of mitigation pathways. Therefore, a thorough understanding of the chemical effects of the emission reductions, changes in photolytic rates and boundary layer due to perturbation of solar radiation, and the effect of meteorological/seasonal changes are needed on a regional basis. Statistical emulators and machine learning approaches can aid the cumbersome process of multi-sector multi-species source attribution.