“…On the other hand, Mackay has pointed out that, for solids, f/fr decreases with increasing melting point (mp) and molecular weight, and a precise relationship between K and S must, therefore, take into account factors such as the melting point, entropy of fusion, and the difference between solid and liquid heat capacities. A step toward this direction has been made by Yalkowsky and Valvani (8, 9), who propose an equation of the type log K = a (log S) + t>(mp) + c…”