“…A characteristic feature of perovskite structures ABO 3 , known as Glazer’s systems, is a variety of tilting effects. , The latter can be caused by external factors, for example, by pressure, by temperature, by a discrepancy between the lattice parameters of a substrate and the material, or by the misfit strain between different layers in complex materials made of stacks of atomic layers. − The unique functionality of several quantum complex materials with perovskite structure, like cuprates, − manganites, , and bismuthates, can be tuned by atomic substitutions, tolerance factor, misfit strain and pressure which control local structural tilts, bond disproportionation, and nanoscale phase separation. A similar complex lattice fluctuations have been identified by extended X-ray absorption fine structure (EXAFS) in BaPb 1– x Bi x O 3 perovskite superconductors showing bond disproportionation and correlated tilts. , …”