Laminated composite materials are commonly used in the aerospace, defense, automotive and sports industries largely due to their high in-plane specific stiffness and strength characteristics. However, their out-of-plane properties are at least two orders of magnitude lower than their in-plane counterparts. In an attempt to increase these out-of-plane properties, carbon nanotubes (CNTs) were introduced into the interlaminar regions as a means of reinforcement. Past literature has focused mainly on the use of CNTs as in interlaminar shear reinforcement whereas the research presented in this paper examines the effects of CNT reinforcement in both interlaminar tension and interlaminar shear loading, as well as the effects these CNTs have on the in-plane material properties. All parts were fabricated using the vacuum assisted resin transfer molding (VARTM) technique. VARTM methods were used to show the applicability of the CNT reinforcement to a wide variety of low-cost, out-of-autoclave applications. Two techniques were developed for dispersing the nanotubes within the interlaminar and intralaminar regions of the composites; metered spray deposition technique, to be used for parts which require a high degree of uniformity in the dispersion of the CNTs over a large area and, CNT doped epoxy infusion in which CNTs are sonicated into the epoxy prior infusion. The doped epoxy infusion method has shown a filtering of the CNTs within the fibers, leading to a gradient in the material properties. Exploiting this filtering phenomenon may allow for targeted, local CNT reinforcement in critical areas of the structure only, leading to more cost effective implementation of CNT reinforcement. The CNT reinforcement of the composites' matrix was found to increase interlaminar tension and shear strength as much as 17% while maintaining, and in some cases enhancing, the in-plane material properties.
Nomenclature
CNTs= carbon nanotubes VARTM = vacuum assisted resin transfer molding SWNT = single-wall nanotubes MWNT = multi-wall nanotubes MSDT = metered spray deposition technique %wt = percentage of carbon nanotubes to composite fiber, by weight ILTS = nominal interlaminar tension strength ILTS max = maximum nominal interlaminar tension strength P max = maximum load w e = semi-elliptical section's cross section width, measured at ellipse's vertex t e = semi-elliptical section's cross section thickness, measured at ellipse's vertex ILSS = interlaminar shear strength ILSS max = maximum interlaminar shear strength w b = short beam shear specimen's cross section width t b = short beam shear specimen's cross section thickness 2 B y = percent bending in in-plane test coupon about its transverse neutral axis ε f = measured longitudinal strain on the front face of an in-plane test coupon ε b = measured longitudinal strain on the back face of an in-plane test coupon με = microstrain E = in-plane tensile (Young's) modulus v = in-plane Poisson's ratio 12 = in-plane shear stress 12 = in-plane shear strain ε l = average measured longitudinal str...